Hydrochloric Acid-Promoted Copper/Iron-Cocatalyzed Deesterificative Oxyphosphorylation of 2-Substituted Acrylates with H-Phosphine Oxides
文献类型：期刊论文
| 作者 | Wang Huabin2,4; Fu Qiang1; Zhang Zhijie1,3; Gao Ming2,4; Ji Jianxin2; Yi Dong1 |
| 刊名 | CHINESE JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2019-08-25 |
| 卷号 | 38期号:8页码:1977-1984 |
| 关键词 | beta-ketophosphine oxides 2-substituted acrylates hydrochloric acid copper/iron-cocatalysis dioxygen |
| ISSN号 | 0253-2786 |
| DOI | 10.6023/cjoc201805027 |
| 产权排序 | 1 |
| 文献子类 | Article |
| 英文摘要 | An unprecedented method for the transformation of 2-substituted acrylates into beta-ketophosphine oxides has successfully been developed via hydrochloric acid-promoted copper/iron-cocatalyzed deesterificative oxyphosphorylation under dioxygen atmosphere, simultaneously inhibiting the formation of the preceding hydroxyphosphorylation products. Through this convenient and practical process, a library of structurally diverse beta-ketophosphine oxides could be selectively and effectively obtained with broad substrate scope and good functional group tolerance under mild conditions, accompanied by chemoselective cleavage of C(sp(2))-C(C=O) bonds. |
| URL标识 | 查看原文 |
| WOS关键词 | BETA-KETOPHOSPHINE OXIDES ; CATALYZED DIRECT OXYPHOSPHORYLATION ; ELECTRON-DEFICIENT ALKENES ; LIGHT PHOTOREDOX CATALYSIS ; ONE-POT SYNTHESIS ; TRANSITION-METAL ; RADICAL OXYPHOSPHORYLATION ; AEROBIC OXYPHOSPHORYLATION ; PHOSPHONATE CARBANIONS ; SELECTIVE SYNTHESIS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| CSCD记录号 | CSCD:6322002 |
| WOS记录号 | WOS:000450199700012 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://210.75.237.14/handle/351003/30180]  |
| 专题 | 国家天然药物工程技术研究中心_天然产物研究 |
| 作者单位 | 1.Southwest Med Univ, Sch Pharm, Luzhou 646000, Peoples R China; 2.Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China; 3.Southwest Med Univ, Drug Discovery Reseach Ctr, Luzhou 646000, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Wang Huabin,Fu Qiang,Zhang Zhijie,et al. Hydrochloric Acid-Promoted Copper/Iron-Cocatalyzed Deesterificative Oxyphosphorylation of 2-Substituted Acrylates with H-Phosphine Oxides[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2019,38(8):1977-1984. |
| APA | Wang Huabin,Fu Qiang,Zhang Zhijie,Gao Ming,Ji Jianxin,&Yi Dong.(2019).Hydrochloric Acid-Promoted Copper/Iron-Cocatalyzed Deesterificative Oxyphosphorylation of 2-Substituted Acrylates with H-Phosphine Oxides.CHINESE JOURNAL OF ORGANIC CHEMISTRY,38(8),1977-1984. |
| MLA | Wang Huabin,et al."Hydrochloric Acid-Promoted Copper/Iron-Cocatalyzed Deesterificative Oxyphosphorylation of 2-Substituted Acrylates with H-Phosphine Oxides".CHINESE JOURNAL OF ORGANIC CHEMISTRY 38.8(2019):1977-1984. |
入库方式： OAI收割
来源：成都生物研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。