Analysis of Compounds Dissolved in Nonpolar Solvents by Electrospray Ionization on Conductive Nanomaterials
文献类型：期刊论文
| 作者 | Xia, Bing; Gao, Yuanji; Ji, Baocheng; Ma, Fengwei; Ding, Lisheng; Zhou, Yan |
| 刊名 | JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
 |
| 出版日期 | 2018-03-01 |
| 卷号 | 29期号:3页码:573-580 |
| 关键词 | Conductive nanomaterials Electrospray ionization Nonpolar solvents |
| ISSN号 | 1044-0305 |
| DOI | 10.1007/s13361-017-1873-y |
| 产权排序 | 1 |
| 文献子类 | Article |
| 英文摘要 | Electrospray ionization mass spectrometry (ESI-MS) technique has limitations in analysis of compounds that are dissolved in nonpolar solvents. In this study, ambient ionization of compounds in solvents that are not "friendly" to electrospray ionization, such as n-hexane, is achieved by conductive nanomaterials spray ionization (CNMSI) on nanomaterial emitters, including carbon nanotubes paper and mesodendritic silver covered metal, which applies high voltages to emitters made of these materials without the assistance of polar solvents. Although the time intensity curves (TIC) commonly vary from 4.5% to 23.7% over analyses, protonated molecular ions were found to be the most abundant species, demonstrating good reproducibility of the technique in terms of ionized species. Higher mass spectrometric responses are observed in analyzing nonpolar systems than polar systems. 2-Methoxyacetophenone, 4-methylacetophenone, benzothiazole, quinolone, and cycloheptanone as low as 2 pg in n-hexane can be directly detected using the developed method. The developed technique expands the analysis capability of ESI-MS for direct, online analysis of nonpolar systems, such as low polarity extracts, normal phase liquid chromatography eluates, and synthetic mixtures. |
| 学科主题 | Spectroscopy ; Instrumentation/analytical Sciences |
| URL标识 | 查看原文 |
| WOS关键词 | MASS-SPECTROMETRY ; PROBE ELECTROSPRAY ; FIELD-EMISSION ; IDENTIFICATION ; NANOTUBES ; MIXTURES ; STRATEGY ; COMPLEX ; URINE ; DRUGS |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry ; Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000426839000016 |
| 出版者 | SPRINGER |
| 源URL | [http://210.75.237.14/handle/351003/30315]  |
| 专题 | 国家天然药物工程技术研究中心_天然产物研究 |
| 作者单位 | Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Bing,Gao, Yuanji,Ji, Baocheng,et al. Analysis of Compounds Dissolved in Nonpolar Solvents by Electrospray Ionization on Conductive Nanomaterials[J]. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,2018,29(3):573-580. |
| APA | Xia, Bing,Gao, Yuanji,Ji, Baocheng,Ma, Fengwei,Ding, Lisheng,&Zhou, Yan.(2018).Analysis of Compounds Dissolved in Nonpolar Solvents by Electrospray Ionization on Conductive Nanomaterials.JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY,29(3),573-580. |
| MLA | Xia, Bing,et al."Analysis of Compounds Dissolved in Nonpolar Solvents by Electrospray Ionization on Conductive Nanomaterials".JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY 29.3(2018):573-580. |
入库方式： OAI收割
来源：成都生物研究所
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