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Bioinspired Catalysis: Self-Assembly of a Protein and DNA as a Catalyst for the Aldol Reaction in Aqueous Media

文献类型：期刊论文

作者Liu, Hongxin1,2; Li, Guangxun1,2; Wang, Ying-wei3; Zhang, Shiqi3; Tang, Zhuo1,2
刊名SYNLETT
出版日期2018-03-01
卷号29期号:5页码:560-565
关键词self-assembly protamine DNA electrostatic interaction bioinspired catalysis aldol reaction
ISSN号0936-5214
DOI10.1055/s-0036-1591854
产权排序1
文献子类Article
英文摘要An interesting bioinspired catalyst formed from readily available DNA and a protein through electrostatic interaction in situ proved to be efficient in catalyzing aldol reactions under mild conditions in water. By using a self-assembling catalytic system formed from protamine and DNA, aldol adducts were obtained with high yields and moderate enantioselectivities. Preliminary experiments demonstrated that the chirality of the DNA could be effectively transferred to the reaction product through the bound molecules or proteins.
学科主题Organic Chemistry ; Polymer Science
URL标识查看原文
WOS关键词ASYMMETRIC CATALYSIS ; SMALL PEPTIDES ; CHORISMATE MUTASE ; IONIC LIQUIDS ; WATER ; PROTAMINE ; ARGININE ; ACIDS ; BASE
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000426600100005
出版者GEORG THIEME VERLAG KG
源URL[http://210.75.237.14/handle/351003/30317]  
专题国家天然药物工程技术研究中心_天然产物研究
作者单位1.Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Sichuan, Peoples R China;
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China;
3.Sichuan Univ, Coll Chem Engn, Chengdu 610041, Sichuan, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Hongxin,Li, Guangxun,Wang, Ying-wei,et al. Bioinspired Catalysis: Self-Assembly of a Protein and DNA as a Catalyst for the Aldol Reaction in Aqueous Media[J]. SYNLETT,2018,29(5):560-565.
APA Liu, Hongxin,Li, Guangxun,Wang, Ying-wei,Zhang, Shiqi,&Tang, Zhuo.(2018).Bioinspired Catalysis: Self-Assembly of a Protein and DNA as a Catalyst for the Aldol Reaction in Aqueous Media.SYNLETT,29(5),560-565.
MLA Liu, Hongxin,et al."Bioinspired Catalysis: Self-Assembly of a Protein and DNA as a Catalyst for the Aldol Reaction in Aqueous Media".SYNLETT 29.5(2018):560-565.

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来源：成都生物研究所

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