A synthetic manganese-calcium cluster similar to the catalyst of Photosystem II: challenges for biomimetic water oxidation
文献类型：期刊论文
| 作者 | Mousazade, Younes; Mohammadi, Mohammad Reza; Bagheri, Robabeh; Bikas, Rahman; Chernev, Petko; Song, Zhenlun; Lis, Tadeusz; Siczek, Milosz; Noshiranzadeh, Nader; Mebs, Stefan |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2020 |
| 卷号 | 49期号:17页码:5597-5605 |
| 关键词 | OXYGEN-EVOLVING COMPLEX OXIDIZING COMPLEX SOLAR-ENERGY MODEL OXIDE PHOTOSYNTHESIS PHOTOLYSIS INSIGHTS |
| DOI | 10.1039/d0dt00536c |
| 英文摘要 | Herein, we report the synthesis, characterization, crystal structure, density functional theory calculations, and water-oxidizing activity of a pivalate Mn-Ca cluster. All of the manganese atoms in the cluster are Mn(iv) ions and have a distorted MnO6 octahedral geometry. Three Mn(iv) ions together with a Ca(ii) ion and four-oxido groups form a cubic Mn3CaO4 unit which is similar to the Mn3CaO4 cluster in the water-oxidizing complex of Photosystem II. Using scanning electron microscopy, transmission electron microscopy, energy dispersive spectrometry, extended X-ray absorption spectroscopy, chronoamperometry, and electrochemical methods, a conversion into nano-sized Mn-oxide is observed for the cluster in the water-oxidation reaction. |
| 学科主题 | Chemistry |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/19658]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Bikas, R (corresponding author), Imam Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin 3414896818, Iran. 2.Najafpour, MM (corresponding author), Inst Adv Studies Basic Sci IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran. 3.Najafpour, MM (corresponding author), Inst Adv Studies Basic Sci IASBS, Dept Chem, Zanjan 4513766731, Iran. 4.Najafpour, MM (corresponding author), Inst Adv Studies Basic Sci IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran. |
| 推荐引用方式 GB/T 7714 | Mousazade, Younes,Mohammadi, Mohammad Reza,Bagheri, Robabeh,et al. A synthetic manganese-calcium cluster similar to the catalyst of Photosystem II: challenges for biomimetic water oxidation[J]. DALTON TRANSACTIONS,2020,49(17):5597-5605. |
| APA | Mousazade, Younes.,Mohammadi, Mohammad Reza.,Bagheri, Robabeh.,Bikas, Rahman.,Chernev, Petko.,...&Najafpour, Mohammad Mahdi.(2020).A synthetic manganese-calcium cluster similar to the catalyst of Photosystem II: challenges for biomimetic water oxidation.DALTON TRANSACTIONS,49(17),5597-5605. |
| MLA | Mousazade, Younes,et al."A synthetic manganese-calcium cluster similar to the catalyst of Photosystem II: challenges for biomimetic water oxidation".DALTON TRANSACTIONS 49.17(2020):5597-5605. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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