Investigation of Losartan Potassium as an eco-friendly corrosion inhibitor for copper in 0.5 M H2SO4
文献类型:期刊论文
作者 | Li, Hao; Zhang, Shengtao; Tan, Bochuan; Qiang, Yujie; Li, Wenpo; Chen, Shijin; Guo, Lei |
刊名 | JOURNAL OF MOLECULAR LIQUIDS
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出版日期 | 2020 |
卷号 | 305 |
关键词 | MILD-STEEL CORROSION SULFURIC-ACID MOLECULAR-DYNAMICS CARBON-STEEL IONIC LIQUIDS ANTICORROSIVE MECHANISM STAINLESS-STEEL CU CORROSION HCL SOLUTION EXTRACT |
DOI | 10.1016/j.molliq.2020.112789 |
英文摘要 | Losartan Potassium (LP) is a commonly used drug for the treatment of hypertension. In this study, the corrosion inhibition performance of LP on copper in 0.5 M H2SO4 was investigated using electrochemicalmethods, surface morphological observation, X-ray photoelectron spectroscopy (XPS), quantum chemical calculation and molecular dynamics (MD) simulation. The electrochemical results show that LP is a type of mixed-type inhibitor that suppresses both cathode and anode reactions by forming a protective film. This film follows the Langmuir adsorption model and mainly depends on chemisorption in this process. XPS analysis confirmed that the adsorption film was due to the formation of coordination compounds between N atoms in the LP molecule and copper. Quantum chemical calculation further confirmed the active centres of N atoms in LP molecules, andMD simulation demonstrated that the inhibitor was adsorbed almost tightly and parallel to the Cu (111) surface. (C) 2020 Elsevier B.V. All rights reserved. |
学科主题 | Chemistry ; Physics |
源URL | [http://ir.nimte.ac.cn/handle/174433/19731] ![]() |
专题 | 2020专题 2020专题_期刊论文 |
作者单位 | 1.Li, WP (corresponding author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China. 2.Qiang, YJ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Li, Hao,Zhang, Shengtao,Tan, Bochuan,et al. Investigation of Losartan Potassium as an eco-friendly corrosion inhibitor for copper in 0.5 M H2SO4[J]. JOURNAL OF MOLECULAR LIQUIDS,2020,305. |
APA | Li, Hao.,Zhang, Shengtao.,Tan, Bochuan.,Qiang, Yujie.,Li, Wenpo.,...&Guo, Lei.(2020).Investigation of Losartan Potassium as an eco-friendly corrosion inhibitor for copper in 0.5 M H2SO4.JOURNAL OF MOLECULAR LIQUIDS,305. |
MLA | Li, Hao,et al."Investigation of Losartan Potassium as an eco-friendly corrosion inhibitor for copper in 0.5 M H2SO4".JOURNAL OF MOLECULAR LIQUIDS 305(2020). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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