Advanced Electrolytes for Fast-Charging High-Voltage Lithium-Ion Batteries in Wide-Temperature Range
文献类型：期刊论文
| 作者 | Zhang, Xianhui; Zou, Lianfeng; Xu, Yaobin; Cao, Xia; Engelhard, Mark H.; Matthews, Bethany E.; Zhong, Lirong; Wu, Haiping; Jia, Hao; Ren, Xiaodi |
| 刊名 | ADVANCED ENERGY MATERIALS
 |
| 出版日期 | 2020 |
| 卷号 | 10期号:22 |
| 关键词 | METAL DISSOLUTION INTERPHASE PROP-1-ENE-1,3-SULTONE TRANSITION EFFICIENCY CARBONATE CATHODE SURFACE CELLS LAYER |
| DOI | 10.1002/aenm.202000368 |
| 英文摘要 | LiNixMnyCo1-x-yO2 (NMC) cathode materials with Ni >= 0.8 have attracted great interest for high energy-density lithium-ion batteries (LIBs) but their practical applications under high charge voltages (e.g., 4.4 V and above) still face significant challenges due to severe capacity fading by the unstable cathode/electrolyte interface. Here, an advanced electrolyte is developed that has a high oxidation potential over 4.9 V and enables NMC811-based LIBs to achieve excellent cycling stability in 2.5-4.4 V at room temperature and 60 degrees C, good rate capabilities under fast charging and discharging up to 3C rate (1C = 2.8 mA cm(-2)), and superior low-temperature discharge performance down to -30 degrees C with a capacity retention of 85.6% at C/5 rate. It is also demonstrated that the electrode/electrolyte interfaces, not the electrolyte conductivity and viscosity, govern the LIB performance. This work sheds light on a very promising strategy to develop new electrolytes for fast-charging high-energy LIBs in a wide-temperature range. |
| 学科主题 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/19781]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | Xu, W (corresponding author), Pacific Northwest Natl Lab, Energy & Environm Directorate, Richland, WA 99354 USA. |
| 推荐引用方式 GB/T 7714 | Zhang, Xianhui,Zou, Lianfeng,Xu, Yaobin,et al. Advanced Electrolytes for Fast-Charging High-Voltage Lithium-Ion Batteries in Wide-Temperature Range[J]. ADVANCED ENERGY MATERIALS,2020,10(22). |
| APA | Zhang, Xianhui.,Zou, Lianfeng.,Xu, Yaobin.,Cao, Xia.,Engelhard, Mark H..,...&Xu, Wu.(2020).Advanced Electrolytes for Fast-Charging High-Voltage Lithium-Ion Batteries in Wide-Temperature Range.ADVANCED ENERGY MATERIALS,10(22). |
| MLA | Zhang, Xianhui,et al."Advanced Electrolytes for Fast-Charging High-Voltage Lithium-Ion Batteries in Wide-Temperature Range".ADVANCED ENERGY MATERIALS 10.22(2020). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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