pi-pi interaction between fluorinated reduced graphene oxide and acridizinium ionic liquid: Synthesis and anti-corrosion application
文献类型：期刊论文
| 作者 | Wu, Yangmin; Zhao, Wenjie; Qiang, Yujie; Chen, Zhengjian; Wang, Liping; Gao, Xiulei; Fang, Zhiwen |
| 刊名 | CARBON
 |
| 出版日期 | 2020 |
| 卷号 | 159页码:292-302 |
| 关键词 | ENHANCED CORROSION PROTECTION EXFOLIATED FLUOROGRAPHENE COATINGS FILMS CONDUCTIVITY RESISTANCE NANOSHEETS BARRIER LITHIUM |
| DOI | 10.1016/j.carbon.2019.12.047 |
| 英文摘要 | Graphene has long been considered a superlative protection material due to its extraordinary characteristics and properties. However, its high electrical conductivity can facilitate the electrochemical corrosion of metal, which strongly limits its anti-corrosion applications. Here, we developed a facile fluorination strategy to suppress the corrosion promotion activity of graphene. Fluorinated reduced graphene oxide (FrGO) exhibited low electrical conductivity (3.643 x 10(-13) S/cm), which proved unable to trigger micro-galvanic corrosion. Furthermore, acridizinium ionic liquid (IL) [MAc]Br was non-covalently grafted on FrGO to achieve the well dispersion in the polymer matrix. Results revealed that FrGO-IL nanohybrid can be stably dispersed in the epoxy resin. Electrochemical impedance spectroscopy revealed that incorporating a small percentage of FrGO-IL into waterborne epoxy matrix effectively improved the corrosion resistance performance of the coating by exerting the superior shielding effect and inhibiting the ability for micro-galvanic corrosion. Moreover, local electrochemical and scratching tests further confirmed that FrGO-IL significantly reinforced the corrosion protection capability of waterborne epoxy coating because the well-dispersed nanohybrid enhanced the integrity of the composite coating, effectively utilizing the labyrinth effect. Our finding could inspire the development of new graphene-based materials with superior protection properties for metal materials. (C) 2019 Elsevier Ltd. All rights reserved. |
| 学科主题 | Chemistry ; Materials Science |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/19793]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Wang, LP (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China. 2.Zhao, WJ |
| 推荐引用方式 GB/T 7714 | Wu, Yangmin,Zhao, Wenjie,Qiang, Yujie,et al. pi-pi interaction between fluorinated reduced graphene oxide and acridizinium ionic liquid: Synthesis and anti-corrosion application[J]. CARBON,2020,159:292-302. |
| APA | Wu, Yangmin.,Zhao, Wenjie.,Qiang, Yujie.,Chen, Zhengjian.,Wang, Liping.,...&Fang, Zhiwen.(2020).pi-pi interaction between fluorinated reduced graphene oxide and acridizinium ionic liquid: Synthesis and anti-corrosion application.CARBON,159,292-302. |
| MLA | Wu, Yangmin,et al."pi-pi interaction between fluorinated reduced graphene oxide and acridizinium ionic liquid: Synthesis and anti-corrosion application".CARBON 159(2020):292-302. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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