Carbonaceous microsphere/nanofiber composite superhydrophilic membrane with enhanced anti-adhesion property towards oil and anionic surfactant: Membrane fabrication and applications
文献类型:期刊论文
作者 | Lv, Yuhuan; Ding, Yajie; Wang, Jianqiang; He, Bing; Yang, Simin; Pan, Kai; Liu, Fu |
刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
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出版日期 | 2020 |
卷号 | 235 |
关键词 | NANOFIBROUS MEMBRANE OIL/WATER SEPARATION OSMOSIS MEMBRANES HYDROTHERMAL CARBONIZATION FOULING RESISTANCE PVDF MEMBRANES POLYDOPAMINE EMULSIONS MICROFILTRATION DEMULSIFICATION |
DOI | 10.1016/j.seppur.2019.116189 |
英文摘要 | Fouling issue is the key obstacle that limited the practical applications of superwetting oil/water separation membrane. Dispersed oil phase and soluble surfactants in the emulsion are the primary foulants during separation of oil/water mixtures. Therefore, developing membranes with anti-adhesion property towards both dispersed phase and surfactant is of great importance. In this study, a superhydrophilic, underwater super-oleophobic composite membrane with excellent antifouling property for separating oil-in-water emulsions stabilized by anionic surfactants was fabricated. Briefly, carboxylated carbonaceous microspheres were synthesized and loaded on nanofibrous membrane through a facile hydrothermal strategy. Acrylic acid was introduced to the hydrothermal process to manipulate the surface charge of carbonaceous microspheres. The fabricated membrane showed excellent anti-adhesion property towards dispersed phase (toluene) due to the improved surface wettability and hydration property. Underwater oil contact angle was up to 160 +/- 1 degrees (e.g., M8-2 membrane). Meanwhile, the fabricated membrane exhibited excellent anti-adhesion performance for oil-in-water emulsions stabilized by anionic surfactants (e.g. sodium laurylsulfonate) due to electrostatic repulsion. Therefore, the membrane can maintain the permeability as high as 41,020 +/- 805 L m(-2) h(-1) bar(-1) even after ten times of usage. The construction strategy and the antifouling analysis presented in the current study may give more opportunities for the understanding of superwetting oil/water separation process. |
学科主题 | Engineering |
源URL | [http://ir.nimte.ac.cn/handle/174433/19866] ![]() |
专题 | 2020专题 2020专题_期刊论文 |
作者单位 | 1.Pan, K 2.Liu, F (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Peoples R China. 3.Wang, JQ |
推荐引用方式 GB/T 7714 | Lv, Yuhuan,Ding, Yajie,Wang, Jianqiang,et al. Carbonaceous microsphere/nanofiber composite superhydrophilic membrane with enhanced anti-adhesion property towards oil and anionic surfactant: Membrane fabrication and applications[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2020,235. |
APA | Lv, Yuhuan.,Ding, Yajie.,Wang, Jianqiang.,He, Bing.,Yang, Simin.,...&Liu, Fu.(2020).Carbonaceous microsphere/nanofiber composite superhydrophilic membrane with enhanced anti-adhesion property towards oil and anionic surfactant: Membrane fabrication and applications.SEPARATION AND PURIFICATION TECHNOLOGY,235. |
MLA | Lv, Yuhuan,et al."Carbonaceous microsphere/nanofiber composite superhydrophilic membrane with enhanced anti-adhesion property towards oil and anionic surfactant: Membrane fabrication and applications".SEPARATION AND PURIFICATION TECHNOLOGY 235(2020). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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