Oxidized impurity in transition metal nitride for improving the hydrogen evolution efficiency of transition metal nitride-based catalyst
文献类型：期刊论文
| 作者 | Qi, Weiliang; Zhou, Ying; Liu, Siqi; Liu, Honghong; Hui, Lok Shu; Turak, Ayse; Wang, Jun; Yang, Minghui |
| 刊名 | APPLIED MATERIALS TODAY
 |
| 出版日期 | 2020 |
| 卷号 | 18 |
| 关键词 | GRAPHITIC CARBON NITRIDE PHOTOCATALYTIC H-2 PRODUCTION NICKEL NITRIDE ENERGY-CONVERSION WATER OXIDATION MODIFIED G-C3N4 OHMIC CONTACT LIGHT COCATALYST NANOSHEETS |
| DOI | 10.1016/j.apmt.2019.100476 |
| 英文摘要 | Transition metal nitrides (TMNs)-based catalyst as promising alternative for precious metal -based catalyst in hydrogen evolution have gained ever increasing research attention. However, the metastable nature of TMNs often results in the inevitable formation of metallic, oxidized and hydroxide impurities during fabrication. The effects of the inevitable impurities over TMNs in hydrogen evolution reaction are still unclear. Herein, choosing Ni3N as a typical example, the effect of oxidized impurity in transition metal nitride for hydrogen evolution has been systematically investigated. The metal oxdie-metal nitride heterojunction which has been in-situ created by calcinations process exhibits obviously improved performance in boosting hydrogen evolution efficiency of semiconductors as compared to metal nitride by forming Z-scheme pathway. Besides, X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR) measurements demonstrate the formation of reductive defects on the surface of semiconductors created by ammonia treatment which also boost the hydrogen evolution efficiency. Therefore, the optimal ternary sample exhibits the highest hydrogen evolution rate (151.5 mu mol g(-1) h(-1)) under solar light irradiation, which is about 54 times higher than that of pure sample. (C) 2019 Elsevier Ltd. All rights reserved. |
| 学科主题 | Materials Science |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/19901]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Liu, SQ 2.Wang, J (corresponding author), Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China. 3.Yang, MH (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Qi, Weiliang,Zhou, Ying,Liu, Siqi,et al. Oxidized impurity in transition metal nitride for improving the hydrogen evolution efficiency of transition metal nitride-based catalyst[J]. APPLIED MATERIALS TODAY,2020,18. |
| APA | Qi, Weiliang.,Zhou, Ying.,Liu, Siqi.,Liu, Honghong.,Hui, Lok Shu.,...&Yang, Minghui.(2020).Oxidized impurity in transition metal nitride for improving the hydrogen evolution efficiency of transition metal nitride-based catalyst.APPLIED MATERIALS TODAY,18. |
| MLA | Qi, Weiliang,et al."Oxidized impurity in transition metal nitride for improving the hydrogen evolution efficiency of transition metal nitride-based catalyst".APPLIED MATERIALS TODAY 18(2020). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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