中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Multilayer boron nitride nanofilm as an effective barrier for atomic oxygen irradiation

文献类型:期刊论文

作者Cheng, Li; Shi, Yanbin; Hao, Yu; Li, Wensheng; Ren, Siming; Wang, Liping
刊名APPLIED SURFACE SCIENCE
出版日期2020
卷号504
关键词THIN-FILMS CORROSION GRAPHENE OXIDATION LAYER TRANSITION SIMULATION RESISTANCE NANOSHEETS POLYMERS
DOI10.1016/j.apsusc.2019.144394
英文摘要Boron nitride (BN) nanofilm, as a structural analogue of graphene, is one of the most promising candidates for an effective anti-oxidation barrier to protect the underlying metal. Herein, the oxidation resistance of monolayer and multilayer BN nanofilms against space atomic oxygen (AO) irradiation is studied systematically. Experimental results reveal that multilayer BN coated Cu foils exhibit superior oxidation resistance against AO irradiation than that of monolayer BN coated ones and bare Cu, resulting from the high impermeability of multilayer films. Density functional theory calculations and molecular dynamics simulations indicate that AO can be absorbed spontaneously on the surface of BN plane and can't move arbitrarily. However, AO can still damage monolayer BN film after long time irradiation, leading to the oxidation of underneath Cu. In comparison to monolayer BN, the multilayer designing of BN may adsorb AO on the top layer, and increases the diffusion difficulties of AO passing layers, which enhances the barrier performance against AO. These results prove that multilayer BN have an important promising implication as one oxidation-inhibiting barrier to anti-AO in space.
学科主题Chemistry ; Materials Science ; Physics
源URL[http://ir.nimte.ac.cn/handle/174433/19944]  
专题2020专题
2020专题_期刊论文
作者单位1.Ren, SM
2.Wang, LP (corresponding author), Chinese Acad Sci, Zhejiang Key Lab Marine Mat & Protect Technol, Key Lab Marine Mat & Related Technol, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China.
推荐引用方式
GB/T 7714
Cheng, Li,Shi, Yanbin,Hao, Yu,et al. Multilayer boron nitride nanofilm as an effective barrier for atomic oxygen irradiation[J]. APPLIED SURFACE SCIENCE,2020,504.
APA Cheng, Li,Shi, Yanbin,Hao, Yu,Li, Wensheng,Ren, Siming,&Wang, Liping.(2020).Multilayer boron nitride nanofilm as an effective barrier for atomic oxygen irradiation.APPLIED SURFACE SCIENCE,504.
MLA Cheng, Li,et al."Multilayer boron nitride nanofilm as an effective barrier for atomic oxygen irradiation".APPLIED SURFACE SCIENCE 504(2020).

入库方式: OAI收割

来源:宁波材料技术与工程研究所

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