A New Sight into Bio-Based Polybenzoxazine: From Tunable Thermal and Mechanical Properties to Excellent Marine Antifouling Performance
文献类型：期刊论文
| 作者 | Lu, Guangming; Dai, Jinyue; Liu, Jingkai; Tian, Shu; Xu, Yongjian; Teng, Na; Liu, Xiaoqing |
| 刊名 | ACS OMEGA
 |
| 出版日期 | 2020 |
| 卷号 | 5期号:7页码:3763-3773 |
| 关键词 | BENZOXAZINE MONOMER BISPHENOL-A POLYMER RESIN PRECURSORS THERMOSETS VANILLIN DESIGN |
| DOI | 10.1021/acsomega.0c00025 |
| 英文摘要 | With the rapid development of bio-based polymers, polybenzoxazine derived from renewable resources has been widely investigated. However, there are few reports on the functional application of bio-based polybenzoxazine based on the special chemical structures of renewable compounds. In this work, an easy approach to prepare the polybenzoxazines with varied thermomechanical properties and excellent marine antifouling performance from renewable resources is presented. After a variety of main-chain-type benzoxazine polymers (MCBPs) were synthesized from the renewable daidzein, furfurylamine, polyetheramine, and paraformaldehyde, their chemical structures were identified by Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy (H-1 NMR). Then, their curing behaviors were monitored by differential scanning calorimetry and rheological tests. Results revealed that the cross-linked MCBPs with varied thermomechanical properties could be easily prepared by adjusting the molar ratio of polyetheramine and furfuramine. Notably, these cured MCBP films demonstrated excellent antibacterial and algaecidal properties due to the presence of daidzein and furan units. This work first presents the new application prospect of bio-based MCBPs, for example, in marine antifouling coatings. |
| 学科主题 | Chemistry |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/19953]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | Liu, XQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Lu, Guangming,Dai, Jinyue,Liu, Jingkai,et al. A New Sight into Bio-Based Polybenzoxazine: From Tunable Thermal and Mechanical Properties to Excellent Marine Antifouling Performance[J]. ACS OMEGA,2020,5(7):3763-3773. |
| APA | Lu, Guangming.,Dai, Jinyue.,Liu, Jingkai.,Tian, Shu.,Xu, Yongjian.,...&Liu, Xiaoqing.(2020).A New Sight into Bio-Based Polybenzoxazine: From Tunable Thermal and Mechanical Properties to Excellent Marine Antifouling Performance.ACS OMEGA,5(7),3763-3773. |
| MLA | Lu, Guangming,et al."A New Sight into Bio-Based Polybenzoxazine: From Tunable Thermal and Mechanical Properties to Excellent Marine Antifouling Performance".ACS OMEGA 5.7(2020):3763-3773. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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