From a Relatively Hydrophobic and Triethylamine (TEA) Adsorption-Selective Core-Shell Heterostructure to a Humidity-Resistant and TEA Highly Selective Sensing Prototype: An Alternative Approach to Improve the Sensing Characteristics of TEA Sensors
文献类型：期刊论文
| 作者 | Fu, Hao; Shao, Hongyun; Wang, Liwei; Jin, Han; Xia, Dehua; Deng, Shengwei; Wang, Yinghui; Chen, Yi; Hua, Changzhou; Liu, Li |
| 刊名 | ACS SENSORS
 |
| 出版日期 | 2020 |
| 卷号 | 5期号:2页码:571-579 |
| 关键词 | P-N HETEROJUNCTION GAS SENSOR ROOM-TEMPERATURE LIGHT IRRADIATION SNO2 NANOTUBES FAST-RESPONSE CARBON PERFORMANCE FILMS FORMALDEHYDE |
| DOI | 10.1021/acssensors.9b02519 |
| 英文摘要 | During the detection of industrial toxic gases, such as triethylamine (TEA), poor selectivity and negative humidity impact are still challenging issues. A frequently reported strategy is to employ molecular sieves or metal-organic framework (MOF) membranes so that interference derived from surrounding gases or water vapor can be blocked. Nevertheless, the decline in the response signal was also observed after coating these membranes. Herein, an alternative strategy that is based on a hydrophobic, TEA adsorption-selective p-n conjunction core-shell heterostructure is proposed and is speculated to simultaneously enhance selectivity, sensitivity, and humidity resistance. To verify the practicability of the proposed strategy, a thickness-tunable nitrogen-doped carbon (N-C) shell-coated alpha-Fe2O3 nano-olive (N-C@alpha-Fe2O3 NO)-based core-shell heterostructure that is obtained via a unique all-vapor-phase processing method is selected as the research example. After forming the core-shell heterostructure, a relatively hydrophobic and TEA adsorption-selective N-C@alpha-Fe2O3 NO surface was experimentally confirmed. Particularly, a chemiresistive sensor that comprises N-C@alpha-Fe2O3 NOs exhibits satisfactory selectivity and response magnitude to TEA when compared with the sensor using alpha-Fe2O3 NOs. The detection limit can even reduce to be 400 ppb at 250 degrees C. Furthermore, the sensor based on N-C@alpha-Fe2O3 NOs shows desirable humidity resistance within the relative humidity (RH) range of 30-90%. For practical usage, a sensing prototype based on the N-C@alpha-Fe2O3 NO probe is fabricated, and its satisfactory sensing performance further confirms the potential for future applications in industrial organic amine detection. These promising results show a bright future in enhancing the humidity resistance and selectivity as well as sensitivity of chemiresistive sensors by simply designing a hydrophobic and target gas adsorption (e.g., TEA) preferred p-n junction core-shell heterostructure. |
| 学科主题 | Chemistry ; Science & Technology - Other Topics |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20052]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Jin, H (corresponding author), Shanghai Jiao Tong Univ, Inst Micronano Sci & Technol, Shanghai 200240, Peoples R China. 2.Wang, LW (corresponding author), Guangxi Univ, Sch Marine Sci, Nanning 530004, Peoples R China. 3.Wang, LW (corresponding author), Guangxi Lab Study Coral Reefs South China Sea, Nanning 530003, Peoples R China. 4.Jin, H (corresponding author), Chinese Acad Sci, Ningbo Mat Sci & Technol Inst, Ningbo 315201, Peoples R China. 5.Jin, H (corresponding author), Southeast Univ, State Key Lab Bioelect, Nanjing 210096, Peoples R China. 6.Zang, L (corresponding author), Univ Utah, Nano Inst Utah, Salt Lake City, UT 84112 USA. 7.Zang, L (corresponding author), Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USA. |
| 推荐引用方式 GB/T 7714 | Fu, Hao,Shao, Hongyun,Wang, Liwei,et al. From a Relatively Hydrophobic and Triethylamine (TEA) Adsorption-Selective Core-Shell Heterostructure to a Humidity-Resistant and TEA Highly Selective Sensing Prototype: An Alternative Approach to Improve the Sensing Characteristics of TEA Sensors[J]. ACS SENSORS,2020,5(2):571-579. |
| APA | Fu, Hao.,Shao, Hongyun.,Wang, Liwei.,Jin, Han.,Xia, Dehua.,...&Zang, Ling.(2020).From a Relatively Hydrophobic and Triethylamine (TEA) Adsorption-Selective Core-Shell Heterostructure to a Humidity-Resistant and TEA Highly Selective Sensing Prototype: An Alternative Approach to Improve the Sensing Characteristics of TEA Sensors.ACS SENSORS,5(2),571-579. |
| MLA | Fu, Hao,et al."From a Relatively Hydrophobic and Triethylamine (TEA) Adsorption-Selective Core-Shell Heterostructure to a Humidity-Resistant and TEA Highly Selective Sensing Prototype: An Alternative Approach to Improve the Sensing Characteristics of TEA Sensors".ACS SENSORS 5.2(2020):571-579. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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