13.34 % Efficiency Non-fullerene All-Small-Molecule Organic Solar Cells Enabled by Modulating the Crystallinity of Donors via a Fluorination Strategy
文献类型：期刊论文
| 作者 | Ge, Jinfeng; Xie, Lingchao; Peng, Ruixiang; Fanady, Billy; Huang, Jiaming; Song, Wei; Yan, Tingting; Zhang, Wenxia; Ge, Ziyi |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2020 |
| 卷号 | 59期号:7页码:2808-2815 |
| 关键词 | ELECTRON-ACCEPTOR POLYMER PERFORMANCE MORPHOLOGY |
| DOI | 10.1002/anie.201910297 |
| 英文摘要 | Non-fullerene all-small-molecule organic solar cells (NFSM-OSCs) have shown potential as OSCs, owing to their high purity, easy synthesis and good reproducibility. However, challenges in the modulation of phase separation morphology have limited their development. Herein, two novel small molecular donors, BTEC-1F and BTEC-2F, derived from the small molecule DCAO3TBDTT, are synthesized. Using Y6 as the acceptor, devices based on non-fluorinated DCAO3TBDTT showed an open circuit voltage (V-oc) of 0.804 V and a power conversion efficiency (PCE) of 10.64 %. Mono-fluorinated BTEC-1F showed an increased V-oc of 0.870 V and a PCE of 11.33 %. The fill factor (FF) of di-fluorinated BTEC-2F-based NFSM-OSC was improved to 72.35 % resulting in a PCE of 13.34 %, which is higher than that of BTEC-1F (61.35 %) and DCAO3TBDTT (60.95 %). To our knowledge, this is the highest PCE for NFSM-OSCs. BTEC-2F had a more compact molecular stacking and a lower crystallinity which enhanced phase separation and carrier transport. |
| 学科主题 | Chemistry |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20230]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Ge, ZY (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 2.Ge, ZY (corresponding author), Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Ge, Jinfeng,Xie, Lingchao,Peng, Ruixiang,et al. 13.34 % Efficiency Non-fullerene All-Small-Molecule Organic Solar Cells Enabled by Modulating the Crystallinity of Donors via a Fluorination Strategy[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020,59(7):2808-2815. |
| APA | Ge, Jinfeng.,Xie, Lingchao.,Peng, Ruixiang.,Fanady, Billy.,Huang, Jiaming.,...&Ge, Ziyi.(2020).13.34 % Efficiency Non-fullerene All-Small-Molecule Organic Solar Cells Enabled by Modulating the Crystallinity of Donors via a Fluorination Strategy.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59(7),2808-2815. |
| MLA | Ge, Jinfeng,et al."13.34 % Efficiency Non-fullerene All-Small-Molecule Organic Solar Cells Enabled by Modulating the Crystallinity of Donors via a Fluorination Strategy".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59.7(2020):2808-2815. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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