Electrochemical Oxygen Reduction to Hydrogen Peroxide via a Two-Electron Transfer Pathway on Carbon-Based Single-Atom Catalysts
文献类型：期刊论文
| 作者 | Sun, Kai; Xu, Wenwen; Lin, Xiao; Tian, Shubo; Lin, Wen-Feng; Zhou, Daojin; Sun, Xiaoming |
| 刊名 | ADVANCED MATERIALS INTERFACES
 |
| 出版日期 | 2020 |
| 关键词 | DIRECT H2O2 PRODUCTION NITROGEN-DOPED CARBON PEM FUEL-CELLS METAL-CATALYSTS ELECTROCATALYTIC SYNTHESIS MOLECULAR-OXYGEN RATIONAL DESIGN ELECTRO-FENTON EFFICIENT PD |
| DOI | 10.1002/admi.202001360 |
| 英文摘要 | Electrochemical reduction of oxygen is considered as a new strategy to achieve decentralized preparation of hydrogen peroxide (H2O2) in a green manner. As a promising new type of catalytic material, carbon-based single-atom catalysts can achieve wide-range adjustments of the electronic structure of the active metal centers while also maximize the utilization of metal atoms, toward electrochemical production of H2O2 from the selective two-electron transfer oxygen reduction reaction (ORR). Herein, starting from the reviewing of characterizing methods and reaction mechanisms of ORR via two-electron and four-electron transfer pathways, the vital role of binding strength between OOH intermediate and active sites in determining the activity and selectivity towards H2O2 production is revealed and illustrated. Currently reported carbon-based single-atom catalysts for H2O2 production are systematically summarized and critically reviewed. Moreover, with the underpinning chemistry to improve the overall efficiency, three aspects concerning the central metal atoms, coordinated atoms, and environmental atoms are comprehensively analyzed. Based on the understanding of the most current progresses, some predictions for future H2O2 production via electrochemical routes are offered, which include catalyst designs at atomic levels, new synthesis strategies and characterization techniques, as well as interfacial superwetting interaction engineering at electrode and device levels. |
| 学科主题 | Chemistry ; Materials Science |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20343]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Lin, WF (corresponding author), Loughborough Univ, Dept Chem Engn, Loughborough LE11 3TU, Leics, England. 2.Zhou, DJ (corresponding author), Beijing Univ Chem Technol, Coll Chem, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China. 3.Xu, WW (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Inst New Energy Technol, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Sun, Kai,Xu, Wenwen,Lin, Xiao,et al. Electrochemical Oxygen Reduction to Hydrogen Peroxide via a Two-Electron Transfer Pathway on Carbon-Based Single-Atom Catalysts[J]. ADVANCED MATERIALS INTERFACES,2020. |
| APA | Sun, Kai.,Xu, Wenwen.,Lin, Xiao.,Tian, Shubo.,Lin, Wen-Feng.,...&Sun, Xiaoming.(2020).Electrochemical Oxygen Reduction to Hydrogen Peroxide via a Two-Electron Transfer Pathway on Carbon-Based Single-Atom Catalysts.ADVANCED MATERIALS INTERFACES. |
| MLA | Sun, Kai,et al."Electrochemical Oxygen Reduction to Hydrogen Peroxide via a Two-Electron Transfer Pathway on Carbon-Based Single-Atom Catalysts".ADVANCED MATERIALS INTERFACES (2020). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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