In Situ Synthesis of Manganese Oxide as an Oxygen-Evolving Catalyst: A New Strategy
文献类型:期刊论文
作者 | Abdi, Zahra; Bagheri, Robabeh; Reza Mohammadi, Mohammad; Song, Zhenlun; Gorlin, Mikaela; Dau, Holger; Najafpour, Mohammad Mahdi |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL
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出版日期 | 2020 |
关键词 | WATER-OXIDIZING COMPLEX FORMATION MECHANISM MN OXIDE OXIDATION EFFICIENT MODEL GOLD XPS |
DOI | 10.1002/chem.202002942 |
英文摘要 | All studies on oxygen-evolution reaction by Mn oxides in the presence of cerium(IV) ammonium nitrate (CAN) have been so far carried out by synthesizing Mn oxides in the first step. And then, followed by the investigation of the Mn oxides in the presence of oxidants for oxygen-evolution reaction (OER). This paper presents a case study of a new and promising strategy for in situ catalyst synthesis by the adding Mn-II to either CAN or KMnO4/CAN solution, resulting in the formation of Mn-based catalysts for OER. The catalysts were characterized by scanning electron microscopy, energy-dispersive spectroscopy, transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy. Both compounds contained nano-sized particles that catalyzed OER in the presence of CAN. The turnover frequencies for both catalysts were 0.02 (mmolO2 /mol(Mn) center dot s). |
学科主题 | Chemistry |
源URL | [http://ir.nimte.ac.cn/handle/174433/20358] ![]() |
专题 | 2020专题 2020专题_期刊论文 |
作者单位 | 1.Najafpour, MM (corresponding author), Inst Adv Studies Basic Sci IASBS, Dept Chem, Zanjan 4513766731, Iran. 2.Gorlin, M (corresponding author), Uppsala Univ, Dept Chem, Angstrom Lab, Box 538, S-75121 Uppsala, Sweden. |
推荐引用方式 GB/T 7714 | Abdi, Zahra,Bagheri, Robabeh,Reza Mohammadi, Mohammad,et al. In Situ Synthesis of Manganese Oxide as an Oxygen-Evolving Catalyst: A New Strategy[J]. CHEMISTRY-A EUROPEAN JOURNAL,2020. |
APA | Abdi, Zahra.,Bagheri, Robabeh.,Reza Mohammadi, Mohammad.,Song, Zhenlun.,Gorlin, Mikaela.,...&Najafpour, Mohammad Mahdi.(2020).In Situ Synthesis of Manganese Oxide as an Oxygen-Evolving Catalyst: A New Strategy.CHEMISTRY-A EUROPEAN JOURNAL. |
MLA | Abdi, Zahra,et al."In Situ Synthesis of Manganese Oxide as an Oxygen-Evolving Catalyst: A New Strategy".CHEMISTRY-A EUROPEAN JOURNAL (2020). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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