Synthesis and Evaluation of Bio-Based Plasticizers from 5-Hydroxymethyl-2-Furancarboxylic Acid for Poly(vinyl chloride)
文献类型：期刊论文
| 作者 | Hao, Yanying; Tian, Anping; Zhu, Jin; Fan, Jinshi; Yang, Yong |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2020 |
| 卷号 | 59期号:40页码:18290-18297 |
| 关键词 | BIOBASED PLASTICIZERS THERMAL-PROPERTIES GREEN PLASTICIZER OIL ESTERS PVC PERFORMANCE BEHAVIOR |
| DOI | 10.1021/acs.iecr.0c03356 |
| 英文摘要 | 5-Hydroxymethyl-2-furancarboxylic acid (HFCA), a promising biomonomer from renewable resources, was used to synthesize two bio-based plasticizers, namely, hexyl 5-((hexanoyloxy)methyl)-2-furancarboxylate (HHMFC) and dihexyl 5,5'-(oxybis(methylene))bis(furan-2-carboxylate) (DHOBFC). The chemical structures of these prepared plasticizers were confirmed using Fourier transform infrared and nuclear magnetic resonance, and then, their plasticization effects on poly(vinyl chloride) (PVC) were also studied. As a result, HFCA-based plasticizers were miscible with PVC and exhibited excellent plasticization performances, compared with commercial dioctyl phthalate. It was noted that HHMFC had a much better plasticizing effect on the PVC film than DHOBFC; however, it displayed a poorer volatility resistance and exudation resistance, which could be attributed to its smaller molecular weight. Besides, because each rigid furan ring of the synthesized plasticizers contained one oxygen atom, the polarity of HFCA-based plasticizers was improved, which inhibited them from migrating from the PVC matrix into nonpolar solvents. Therefore, the HFCA-based plasticizers have good potential as primary plasticizers for PVC. |
| 学科主题 | Engineering |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20430]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Yang, Y (corresponding author), Chinese Acad Sci, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 2.Fan, JS (corresponding author), Qingdao Univ Sci & Technol, Coll Marine Sci & Biol Engn, Qingdao 266042, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Hao, Yanying,Tian, Anping,Zhu, Jin,et al. Synthesis and Evaluation of Bio-Based Plasticizers from 5-Hydroxymethyl-2-Furancarboxylic Acid for Poly(vinyl chloride)[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(40):18290-18297. |
| APA | Hao, Yanying,Tian, Anping,Zhu, Jin,Fan, Jinshi,&Yang, Yong.(2020).Synthesis and Evaluation of Bio-Based Plasticizers from 5-Hydroxymethyl-2-Furancarboxylic Acid for Poly(vinyl chloride).INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(40),18290-18297. |
| MLA | Hao, Yanying,et al."Synthesis and Evaluation of Bio-Based Plasticizers from 5-Hydroxymethyl-2-Furancarboxylic Acid for Poly(vinyl chloride)".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.40(2020):18290-18297. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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