A feasible method to improve the protection ability of metal by functionalized carbon dots as environment-friendly corrosion inhibitor
文献类型:期刊论文
作者 | Ye, Yuwei; Zhang, Dawei; Zou, Yangjun; Zhao, Haichao; Chen, Hao |
刊名 | JOURNAL OF CLEANER PRODUCTION
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出版日期 | 2020 |
卷号 | 264 |
关键词 | MILD-STEEL CORROSION HCL SOLUTION ANTICORROSIVE MECHANISM IONIC LIQUIDS GREEN EXTRACT DERIVATIVES GRAPHENE NITROGEN OXIDE |
DOI | 10.1016/j.jclepro.2020.121682 |
英文摘要 | A green inhibitor of N-doped carbon dots (N-CDs) was obtained from the reaction between citric acid and L-histidine. Then, a series of professional equipment was selected to evaluate their structure and corrosion protective behaviors in HCl solution. Quantum chemistry and molecular dynamics were chosen to discuss the inhibition mechanism of N-CDs. Electrochemical results showed that the N-CDs exhibited super corrosion protection to metal because it could form dense and ordered adsorption film on metal surface. Compared with citric acid and L-histidine inhibitors, the inhibition efficiency of N-CDs was more than 90% at 100 mg L-1. Based on the calculation of quantum chemistry and molecular dynamics, the low energy gap (Delta E = 0.0680 eV) and high binding energy (E-binding = 190.85 kJ.mol(-1)) of N-CDs indicated the strong chemisorption on metal substrate, which fully explained the inhibition mechanism of N-CDs at molecular/atomic level. (C) 2020 Elsevier Ltd. All rights reserved. |
学科主题 | Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology |
源URL | [http://ir.nimte.ac.cn/handle/174433/20590] ![]() |
专题 | 2020专题 2020专题_期刊论文 |
作者单位 | 1.Chen, H (corresponding author), Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Ganzhou 341000, Peoples R China. 2.Ye, YW |
推荐引用方式 GB/T 7714 | Ye, Yuwei,Zhang, Dawei,Zou, Yangjun,et al. A feasible method to improve the protection ability of metal by functionalized carbon dots as environment-friendly corrosion inhibitor[J]. JOURNAL OF CLEANER PRODUCTION,2020,264. |
APA | Ye, Yuwei,Zhang, Dawei,Zou, Yangjun,Zhao, Haichao,&Chen, Hao.(2020).A feasible method to improve the protection ability of metal by functionalized carbon dots as environment-friendly corrosion inhibitor.JOURNAL OF CLEANER PRODUCTION,264. |
MLA | Ye, Yuwei,et al."A feasible method to improve the protection ability of metal by functionalized carbon dots as environment-friendly corrosion inhibitor".JOURNAL OF CLEANER PRODUCTION 264(2020). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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