High-Performance, Biobased, Degradable Polyurethane Thermoset and Its Application in Readily Recyclable Carbon Fiber Composites
文献类型：期刊论文
| 作者 | Wang, Binbo; Ma, Songqi; Xu, Xiwei; Li, Qiong; Yu, Tao; Wang, Sheng; Yan, Shifeng; Liu, Yanlin; Zhu, Jin |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2020 |
| 卷号 | 8期号:30页码:11162-11170 |
| 关键词 | ACETAL LINKAGES SYNTHESIS EPOXY VITRIMER FACILE SYNTHESIS MONOMER TEMPERATURE RESINS DIACETAL POLYMER EUGENOL GREEN |
| DOI | 10.1021/acssuschemeng.0c02330 |
| 英文摘要 | Carbon fiber (CF) reinforced polyurethane (PU) composites have attracted increasing attention in recent years. It is still a challenge to recycle the CF reinforced composites, and there is no report on the recycling of CF from PU matrix. In this paper, for the first time, a readily recyclable CF reinforced PU composite was prepared based on a biobased acetal diol, 2-(4-hydroxy-3-methoxyphenyl)-1,3-dioxan-5-ol (HMDO). The acetal diol was synthesized from the lignin derivative vanillin and was used to react with hexamethylene diisocyanate trimer to prepare the PU thermoset (PU-HMDO). On account of the cleavable acetal groups, the PU-HMDO could be decomposed within 40 min in low-concentration acidic solution completely. In addition, the heterocyclic structures of acetal and isocyanurate resulted in excellent mechanical and thermal properties of PU-HMDO. The tensile strength was 68 MPa, the elongation at break was 7.9%, and the glass transition temperature (T-g) was 130 degrees C, which are comparable to those of a PU thermoset (PU-BPA) from commercially available diol bisphenol A (BPA). The thermal stability of PU-HMDO was even higher than that of PU-BPA. The PU-HMDO-based CF composite exhibited similar mechanical properties to the PU-BPA-based CF composite, and CF could be reclaimed with maintained microscale morphology, chemical structures, and mechanical properties under mild acid conditions. This work will open a door to develop readily recyclable PU-based CF composites. |
| 学科主题 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20604]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Ma, SQ 2.Yan, SF (corresponding author), Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China. 3.Liu, YL (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Div Polymers & Composites, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wang, Binbo,Ma, Songqi,Xu, Xiwei,et al. High-Performance, Biobased, Degradable Polyurethane Thermoset and Its Application in Readily Recyclable Carbon Fiber Composites[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(30):11162-11170. |
| APA | Wang, Binbo.,Ma, Songqi.,Xu, Xiwei.,Li, Qiong.,Yu, Tao.,...&Zhu, Jin.(2020).High-Performance, Biobased, Degradable Polyurethane Thermoset and Its Application in Readily Recyclable Carbon Fiber Composites.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(30),11162-11170. |
| MLA | Wang, Binbo,et al."High-Performance, Biobased, Degradable Polyurethane Thermoset and Its Application in Readily Recyclable Carbon Fiber Composites".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.30(2020):11162-11170. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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