Synthesis of well-shaped and high-crystalline Ce-based metal organic framework for CO2/CH4 separation
文献类型：期刊论文
| 作者 | Zhou, Junjie; Liu, Hao; Lin, Yichao; Zhou, Chen; Huang, Aisheng |
| 刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| 出版日期 | 2020 |
| 卷号 | 302 |
| 关键词 | CARBON-DIOXIDE CAPTURE OXYGEN |
| DOI | 10.1016/j.micromeso.2020.110224 |
| 英文摘要 | A well-shaped Ce (IV)-based metal organic framework (Ce-BDC) is prepared under solvothermal method. The influence of synthesis time, temperature and the amount of acetic acid (HAc) as a modulator is studied to develop a new strategy for the synthesis of well-shaped Ce-based MOF. The relationship between the synthesis parameters and morphology as well as crystallinity of Ce-BDC is investigated by XRD and SEM. Furthermore, the obtained well-shaped Ce-BDC shows a CO2 uptake capacity of 2.28 mmol g(-1) at 0 degrees C and 1.0 bar. Meanwhile, the breakthrough curve behaviors of Ce-BDC are investigated for a CO2/CH4 and CO2/N-2 mixture gas. It is found that the Ce-based MOF adsorbs CO 2 under ambient temperature and pressure, but completely excludes CH4 and N-2, suggesting that it is a promising adsorbent for efficient separation of CO2 from natural gas. |
| 学科主题 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20623]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Zhou, C 2.Huang, AS (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Inst New Energy Technol, 1219 Zhongguan Rd, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Zhou, Junjie,Liu, Hao,Lin, Yichao,et al. Synthesis of well-shaped and high-crystalline Ce-based metal organic framework for CO2/CH4 separation[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2020,302. |
| APA | Zhou, Junjie,Liu, Hao,Lin, Yichao,Zhou, Chen,&Huang, Aisheng.(2020).Synthesis of well-shaped and high-crystalline Ce-based metal organic framework for CO2/CH4 separation.MICROPOROUS AND MESOPOROUS MATERIALS,302. |
| MLA | Zhou, Junjie,et al."Synthesis of well-shaped and high-crystalline Ce-based metal organic framework for CO2/CH4 separation".MICROPOROUS AND MESOPOROUS MATERIALS 302(2020). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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