Effect of gas-condensed phase synergistic system of 9,10-dihydro-9-oxo-10-phosphaphenanthrene-10-oxide and polydopamine on flame retardancy of epoxy resin
文献类型:期刊论文
作者 | Xu, Yao; Sun, Jinhao; Qian, Lijun; Li, Juan |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2020 |
卷号 | 138期号:3 |
关键词 | OXYGEN-REDUCTION NANOPARTICLES NANOSHEETS |
DOI | 10.1002/app.49698 |
英文摘要 | Polydopamine (PDA) was prepared by using dopamine which has good charring ability. The PDA was used as an environmentally friendly flame retardant and combined with 9,10-dihydro-9-oxo-10-phosphaphenanthrene-10-oxide (DOPO) to improve the flame retardancy of epoxy (EP) resin. The flame retardancy and thermal stability of EP composites were researched by UL-94 vertical burning, limiting oxygen index (LOI), cone calorimetry tests, and thermal gravimetric analyzer. Adding DOPO alone requires 6% to make EP obtain the UL-94 V0. If DOPO and PDA are combined, only 4% is needed to make EP obtain the UL-94 V0, which suggests that there is good synergistic effect between them. Moreover, the peak of heat release rate of EP/DOPO/PDA composites is less than that of EP/DOPO composites. The reactions among EP, DOPO, and PDA reduce the release of combustible gases at the early stage of degradation; at the same time, DOPO volatilize to the gas phase, quench the free radicals, and the combustion can be stopped. In addition, due to the decrease of the amount of PDA/DOPO, the EP composite can get a higher glass transition temperature, but due to the aggregation of PDA in EP, the tensile property of EP composite decreases. |
学科主题 | Polymer Science |
源URL | [http://ir.nimte.ac.cn/handle/174433/20632] ![]() |
专题 | 2020专题 2020专题_期刊论文 |
作者单位 | Li, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo Key Lab Polymer Mat, Ningbo 315201, Zhejiang, Peoples R China. |
推荐引用方式 GB/T 7714 | Xu, Yao,Sun, Jinhao,Qian, Lijun,et al. Effect of gas-condensed phase synergistic system of 9,10-dihydro-9-oxo-10-phosphaphenanthrene-10-oxide and polydopamine on flame retardancy of epoxy resin[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2020,138(3). |
APA | Xu, Yao,Sun, Jinhao,Qian, Lijun,&Li, Juan.(2020).Effect of gas-condensed phase synergistic system of 9,10-dihydro-9-oxo-10-phosphaphenanthrene-10-oxide and polydopamine on flame retardancy of epoxy resin.JOURNAL OF APPLIED POLYMER SCIENCE,138(3). |
MLA | Xu, Yao,et al."Effect of gas-condensed phase synergistic system of 9,10-dihydro-9-oxo-10-phosphaphenanthrene-10-oxide and polydopamine on flame retardancy of epoxy resin".JOURNAL OF APPLIED POLYMER SCIENCE 138.3(2020). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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