Fully Bio-based Micro-cellulose Incorporated Poly(butylene 2,5-furandicarboxylate) Transparent Composites: Preparation and Characterization
文献类型：期刊论文
| 作者 | Mahmud, Sakil; Long, Yu; Abu Taher, Muhammad; Hu, Han; Zhang, Ruoyu; Zhu, Jin |
| 刊名 | FIBERS AND POLYMERS
 |
| 出版日期 | 2020 |
| 卷号 | 21期号:7页码:1550-1559 |
| 关键词 | MECHANICAL-PROPERTIES MICROCRYSTALLINE CELLULOSE CRYSTALLIZATION BEHAVIOR POLYLACTIC ACID BARRIER FILMS CRYSTALLINITY COPOLYMERS BLOCK |
| DOI | 10.1007/s12221-020-9610-8 |
| 英文摘要 | Poly(butylene 2,5-furandicarboxylate) (PBF) derived from 2,5-furandicarboxylic acid (FDCA) is an emerging bio-based alipharomatic polyester that is expected to replace its fossil-based terephthalate and naphthate homologues. PBF holds excellent gas barrier properties, but its slow rate of crystallization might restrict wider applications. To improve the rate of crystalization, it was melt-blended with crystalline micro-cellulose (CMC) to prepare a composite through twin-screw extrusion. To ensure environmental friendly conditions, neither chemicals to modify fibers nor compatibilizers to improve the filler/matrix interaction were used. Size exclusion chromatography (SEC), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermo-gravimetric analysis (TGA) and X-ray diffraction (XRD) were used to characterize the composite. It was observed that a longer blending duration (cyclic mode) leads to a greater reduction in molecular weight (Mw) in the presence of CMC, which can be avoided by using a shorter blending duration (direct mode). The mechanical properties of the composite showed an increase in Young's modulus by approximately 23 % and 36 % with respect to reference PBF for the cyclic and direct mode respectively. It was further observed that, although the elongation at break and tensile strength has decreased, it has improved gas barrier properties. Thermal analysis shows faster nucleation of PBF in the presence of CMC with a minor effect on its thermal degradation. |
| 学科主题 | Materials Science ; Polymer Science |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20674]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Zhang, RY 2.Zhu, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Mahmud, Sakil,Long, Yu,Abu Taher, Muhammad,et al. Fully Bio-based Micro-cellulose Incorporated Poly(butylene 2,5-furandicarboxylate) Transparent Composites: Preparation and Characterization[J]. FIBERS AND POLYMERS,2020,21(7):1550-1559. |
| APA | Mahmud, Sakil,Long, Yu,Abu Taher, Muhammad,Hu, Han,Zhang, Ruoyu,&Zhu, Jin.(2020).Fully Bio-based Micro-cellulose Incorporated Poly(butylene 2,5-furandicarboxylate) Transparent Composites: Preparation and Characterization.FIBERS AND POLYMERS,21(7),1550-1559. |
| MLA | Mahmud, Sakil,et al."Fully Bio-based Micro-cellulose Incorporated Poly(butylene 2,5-furandicarboxylate) Transparent Composites: Preparation and Characterization".FIBERS AND POLYMERS 21.7(2020):1550-1559. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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