Influences of Bridge Group on Thermal and Mechanical Properties of Epoxy Resins
文献类型:期刊论文
作者 | Liu Yuan; Zhao Jun; Liu Ai-Qin; Liu Xiao-Qing; Luo Jun |
刊名 | POLYMER-KOREA
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出版日期 | 2020 |
卷号 | 44期号:4页码:415-424 |
关键词 | PHYSICAL-PROPERTIES STERIC HINDRANCE FTIR BEHAVIOR SYSTEMS |
DOI | 10.7317/pk.2020.44.4.415 |
英文摘要 | In order to obtain thermosetting epoxy resin, it is the prerequisite condition that the epoxy precursor must contain at least two epoxy groups. Thus, bridge group is needed to link the epoxy groups, and naturally, the chemical structure of the bridge group may also influence the thermomechanical performances of the cured epoxy resin. However, literature about the effects of bridge group on properties of cured epoxy is seldom published. To fill the gap, three model epoxy monomers containing different bridge groups have been synthesized from 4,4'-dihydroxydiphenyl, 1,1-bis(4-hydroxyphenyl)cyclohexane and bisphenol A in this work. After chemical structure confirmation, all of the monomers are cured by methylhexahydrophthalic anhydride (HMMPA), and the properties of the obtained cured network are evaluated by differential scanning calorimetry (DSC), dynamic thermomechanical analysis (DMA), tensile test and scanning electron microscope (SEM). The results show that bulky bridge group can effectively increase the glass transition temperature, enhance the tensile strength, and enlarge elongation at break of the cured epoxy resin. |
学科主题 | Polymer Science |
源URL | [http://ir.nimte.ac.cn/handle/174433/20676] ![]() |
专题 | 2020专题 2020专题_期刊论文 |
作者单位 | Luo, J (corresponding author), Guiyang Univ, Engn Res Ctr Mat Protect Wear & Corros Guizhou Pr, Guiyang 550005, Peoples R China. |
推荐引用方式 GB/T 7714 | Liu Yuan,Zhao Jun,Liu Ai-Qin,et al. Influences of Bridge Group on Thermal and Mechanical Properties of Epoxy Resins[J]. POLYMER-KOREA,2020,44(4):415-424. |
APA | Liu Yuan,Zhao Jun,Liu Ai-Qin,Liu Xiao-Qing,&Luo Jun.(2020).Influences of Bridge Group on Thermal and Mechanical Properties of Epoxy Resins.POLYMER-KOREA,44(4),415-424. |
MLA | Liu Yuan,et al."Influences of Bridge Group on Thermal and Mechanical Properties of Epoxy Resins".POLYMER-KOREA 44.4(2020):415-424. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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