Synthesis and Properties Investigation of Thiophene-aromatic Polyesters: Potential Alternatives for the 2,5-Furandicarboxylic Acid-based Ones
文献类型:期刊论文
作者 | Wang, Jing-Gang; Zhang, Xiao-Qin; Shen, Ang; Zhu, Jin; Song, Ping-An; Wang, Hao; Liu, Xiao-Qing |
刊名 | CHINESE JOURNAL OF POLYMER SCIENCE |
出版日期 | 2020 |
卷号 | 38期号:10页码:1082-1091 |
关键词 | RENEWABLE RESOURCES 2,5-THIOPHENEDICARBOXYLIC ACID CRYSTALLIZATION BEHAVIOR PHYSICAL-PROPERTIES FUTURE-PROSPECTS BIO COPOLYESTERS DEGRADATION TRANSPORT TEMPERATURE |
DOI | 10.1007/s10118-020-2438-2 |
英文摘要 | In order to explore new substitutes for 2,5-furandicarboxylic acid (FDCA) or poly(ethylene 2,5-furandicarboxylate) (PEF) and try to develop more ideal bio-based polyesters, several thiophene-aromatic polyesters (PETH, PPTH, PBTH, and PHTH) were synthesized from dimethyl thiophene-2,5-dicarboxylate (DMTD) and different diols, including ethylene glycol, 1,3-propanediol, 1,4-butanediol, and 1,6-hexanediol. The chemical structures of obtained polyesters were confirmed by nuclear magnetic resonance spectroscopy (H-1-NMR and(13)C-NMR). Determined by GPC measurement, their average molecular weight (M-w) varied from 5.22 x 10(4)g/mol to 7.94 x 10(4)g/mol with the molar-mass dispersity of 1.50-2.00. Based on the DSC and TGA results, the synthesized polyesters PETH, PPTH, and PBTH displayed comparable or even better thermal properties when compared with their FDCA-based analogues. From PETH to PHTH, theirT(g)varied from 64.6 degrees C to -1 xC whileT(5%)ranged from 409 degrees C to 380 degrees C in nitrogen atmosphere. PETH showed elongation at break as high as 378%, tensile strength of 67 MPa, and tensile modulus of 1800 MPa. Meanwhile, the CO(2)and O(2)barrier of PETH was 12.0 and 6.6 folds higher than those of PET, respectively, and similar to those of PEF. Considering the overall properties, the synthesized thiophene-aromatic polyesters, especially PETH, showed great potential to be used as an excellent bio-based packaging material in the future. |
学科主题 | Polymer Science |
源URL | [http://ir.nimte.ac.cn/handle/174433/20732] |
专题 | 2020专题 2020专题_期刊论文 |
作者单位 | Liu, XQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Wang, Jing-Gang,Zhang, Xiao-Qin,Shen, Ang,et al. Synthesis and Properties Investigation of Thiophene-aromatic Polyesters: Potential Alternatives for the 2,5-Furandicarboxylic Acid-based Ones[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2020,38(10):1082-1091. |
APA | Wang, Jing-Gang.,Zhang, Xiao-Qin.,Shen, Ang.,Zhu, Jin.,Song, Ping-An.,...&Liu, Xiao-Qing.(2020).Synthesis and Properties Investigation of Thiophene-aromatic Polyesters: Potential Alternatives for the 2,5-Furandicarboxylic Acid-based Ones.CHINESE JOURNAL OF POLYMER SCIENCE,38(10),1082-1091. |
MLA | Wang, Jing-Gang,et al."Synthesis and Properties Investigation of Thiophene-aromatic Polyesters: Potential Alternatives for the 2,5-Furandicarboxylic Acid-based Ones".CHINESE JOURNAL OF POLYMER SCIENCE 38.10(2020):1082-1091. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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