Flower-like FeS Coated with Heteroatom (S,N)-Doped Carbon as Highly Active and Durable Oxygen Reduction Electrocatalysts
文献类型：期刊论文
| 作者 | Yuan, Yao; Li, Rongrong; Thomas, Tiju; Chen, Jian; Yang, Minghui |
| 刊名 | CHEMELECTROCHEM
 |
| 出版日期 | 2020 |
| 卷号 | 7期号:11页码:2433-2439 |
| 关键词 | DOPED GRAPHENE CATALYSTS NITROGEN SULFUR IRON XPS NANOPARTICLES NANOSHEETS |
| DOI | 10.1002/celc.202000156 |
| 英文摘要 | Developing viable substitutes for noble metal electrocatalysts is an important activity, since it enables the movement to a cleaner energy future. Few FeS-based catalysts have been reported as an oxygen reduction reaction (ORR) catalyst in the past and it does not have the combination of stability, conductivity and reactivity that makes it a viable option. Here, flower-like FeS covered by ultrathin S,N co-doped carbon layer (FeS@C) displays outstanding electrocatalytic ORR performance in alkaline media. The optimum FeS@C-800 sample outperforms undoped commercial FeS and standard Pt/C catalysts with a high positive half-wave potential (E-1/2=0.80 Vvs. RHE), high limiting current density (6.4 mA cm(-2)), complete 4-electron reduction, superior tolerance to methanol and excellent durability towards ORR. The S,N co-doped carbon layers could not only enhance the conductivity and durability, but also further contribute to the improvement of ORR activity through synergistic effect with FeS. The FeS@C also promotes performance as the air cathode in a Zn-air battery, which exhibits higher power density than Pt/C. Hence the reported catalyst holds prospects for use as a high performance electrocatalyst for ORR. |
| 学科主题 | Electrochemistry |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/20752]  |
| 专题 | 2020专题 2020专题_期刊论文 |
| 作者单位 | 1.Chen, J (corresponding author), Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China. 2.Yang, MH (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Solid State Funct Mat Res Lab, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Yuan, Yao,Li, Rongrong,Thomas, Tiju,et al. Flower-like FeS Coated with Heteroatom (S,N)-Doped Carbon as Highly Active and Durable Oxygen Reduction Electrocatalysts[J]. CHEMELECTROCHEM,2020,7(11):2433-2439. |
| APA | Yuan, Yao,Li, Rongrong,Thomas, Tiju,Chen, Jian,&Yang, Minghui.(2020).Flower-like FeS Coated with Heteroatom (S,N)-Doped Carbon as Highly Active and Durable Oxygen Reduction Electrocatalysts.CHEMELECTROCHEM,7(11),2433-2439. |
| MLA | Yuan, Yao,et al."Flower-like FeS Coated with Heteroatom (S,N)-Doped Carbon as Highly Active and Durable Oxygen Reduction Electrocatalysts".CHEMELECTROCHEM 7.11(2020):2433-2439. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。