Exploring the relationship between polycyclic aromatic hydrocarbons and sedimentary organic carbon in three Chinese lakes
文献类型：期刊论文
| ; | |
| 作者 | Fengchang Wu; Libin Xu; Yongge Sun; Haiqing Liao; Xiaoli Zhao; Jianyang Guo |
| 刊名 | Journal of Soils and Sediments
 ; Journal of Soils and Sediments
|
| 出版日期 | 2012 ; 2012 |
| 卷号 | 12期号:5页码:774-783 |
| 关键词 | Lake Sediment Lake Sediment organic Component polycyclic Aromatic Hydrocarbon rock-eval Pyrolysis organic Component polycyclic Aromatic Hydrocarbon rock-eval Pyrolysis |
| 英文摘要 | Purpose Previous studies have shown a positive correlation
between concentrations of polycyclic aromatic hydrocarbons (PAHs) and total organic carbon (TOC) in lake sediments. However, with respect to the complex organic matter in recent sediments, it is still unclear which part of TOC plays a key role in controlling PAHs distributions in natural sediments. The aim of this study was to examine the relationships between PAHs and TOC components of different origins in lake sediments.
Materials and methods Sediment cores from three Chinese lakes with different trophic conditions—Lakes Bosten, Dianchi, and Poyang—were collected using a piston core sampler. The cores were sectioned into 1- or 2-cm intervals immediately after collection and transported on ice to the laboratory where they were stored at −20 °C. The subsamples
were freeze-dried and ground with a mortar and pestle for analyses. PAHs were analyzed by GC–MS and TOC was determined with a PE elemental analyzer after the removal of carbonates. Rock-Eval 6 pyrolysis technique was used to deconvolute the TOC in the sediments into free and volatile hydrocarbons (S1), kerogen-derived hydrocarbons (S2), and residual carbon (RC); S2 was further separated into thermal less stable macromolecular organic matter (S2a) and high
molecular weight kerogens (S2b).
Results and discussion Positive correlations between TOC and PAHs were observed in these lakes. Results show that the more labile, minor components of TOC (S1 and S2a) played a more important role in controlling PAH distributions than the major components of TOC (S2b and RC), probably due to the different accessibilities of the organic
components. The algae-derived organic carbon had a greater influence on the distribution of low molecular weight PAHs than that of high molecular weight PAHs in sediments. This suggests that PAHs scavenging in the water column by algae is mainly targeted at low molecular weight PAHs, and that preferential scavenging of low molecular weight PAHs may be due to the different atmospheric phases of low and high molecular weight PAHs.
Conclusions Algal scavenging had an important influence on the PAH concentrations, especially the lower molecular weight PAH concentrations in the lake sediments. The results suggest that PAH concentrations and their molecular ratios in lake sediments may neither accurately represent the pollution history of PAHs, nor the origin PAHs source differentiation. This study has significant implications for understanding the roles of organic matter in affecting the distributions of PAHs and other similar organic pollutants in lake sediments. ; Purpose Previous studies have shown a positive correlation
between concentrations of polycyclic aromatic hydrocarbons (PAHs) and total organic carbon (TOC) in lake sediments. However, with respect to the complex organic matter in recent sediments, it is still unclear which part of TOC plays a key role in controlling PAHs distributions in natural sediments. The aim of this study was to examine the relationships between PAHs and TOC components of different origins in lake sediments.
Materials and methods Sediment cores from three Chinese lakes with different trophic conditions—Lakes Bosten, Dianchi, and Poyang—were collected using a piston core sampler. The cores were sectioned into 1- or 2-cm intervals immediately after collection and transported on ice to the laboratory where they were stored at −20 °C. The subsamples
were freeze-dried and ground with a mortar and pestle for analyses. PAHs were analyzed by GC–MS and TOC was determined with a PE elemental analyzer after the removal of carbonates. Rock-Eval 6 pyrolysis technique was used to deconvolute the TOC in the sediments into free and volatile hydrocarbons (S1), kerogen-derived hydrocarbons (S2), and residual carbon (RC); S2 was further separated into thermal less stable macromolecular organic matter (S2a) and high
molecular weight kerogens (S2b).
Results and discussion Positive correlations between TOC and PAHs were observed in these lakes. Results show that the more labile, minor components of TOC (S1 and S2a) played a more important role in controlling PAH distributions than the major components of TOC (S2b and RC), probably due to the different accessibilities of the organic
components. The algae-derived organic carbon had a greater influence on the distribution of low molecular weight PAHs than that of high molecular weight PAHs in sediments. This suggests that PAHs scavenging in the water column by algae is mainly targeted at low molecular weight PAHs, and that preferential scavenging of low molecular weight PAHs may be due to the different atmospheric phases of low and high molecular weight PAHs.
Conclusions Algal scavenging had an important influence on the PAH concentrations, especially the lower molecular weight PAH concentrations in the lake sediments. The results suggest that PAH concentrations and their molecular ratios in lake sediments may neither accurately represent the pollution history of PAHs, nor the origin PAHs source differentiation. This study has significant implications for understanding the roles of organic matter in affecting the distributions of PAHs and other similar organic pollutants in lake sediments. |
| 语种 | 英语 ; 英语 |
| 源URL | [http://ir.gyig.ac.cn/handle/42920512-1/10992]  |
| 专题 | 地球化学研究所_环境地球化学国家重点实验室 |
| 作者单位 | 1.State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, People’s Republic of China 2.Institute of Environmental and Biogeochemistry, Department of Earth Sciences, Zhejiang University, Hangzhou 310027, People’s Republic of China 3.State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, People’s Republic of China |
| 推荐引用方式 GB/T 7714 | Fengchang Wu,Libin Xu,Yongge Sun,et al. Exploring the relationship between polycyclic aromatic hydrocarbons and sedimentary organic carbon in three Chinese lakes, Exploring the relationship between polycyclic aromatic hydrocarbons and sedimentary organic carbon in three Chinese lakes[J]. Journal of Soils and Sediments, Journal of Soils and Sediments,2012, 2012,12, 12(5):774-783, 774-783. |
| APA | Fengchang Wu,Libin Xu,Yongge Sun,Haiqing Liao,Xiaoli Zhao,&Jianyang Guo.(2012).Exploring the relationship between polycyclic aromatic hydrocarbons and sedimentary organic carbon in three Chinese lakes.Journal of Soils and Sediments,12(5),774-783. |
| MLA | Fengchang Wu,et al."Exploring the relationship between polycyclic aromatic hydrocarbons and sedimentary organic carbon in three Chinese lakes".Journal of Soils and Sediments 12.5(2012):774-783. |
入库方式： OAI收割
来源：地球化学研究所
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