Ligand-Sharing-Mediated Synthesis of Intermetallic FeM Clusters Embedded in Ultrathin gamma-Fe2O3 Nanosheets
文献类型：期刊论文
| 作者 | Liu, Rui2; Chen, Yanan2; Zhao, Huachao; Sun, Jiefang3; He, Zuoliang2; Shan, Wanyu2; Li, Gang; Liu, Jingfu; Jiang, Guibin
|
| 刊名 | ADVANCED FUNCTIONAL MATERIALS
 |
| 出版日期 | 2020 |
| 卷号 | 30期号:5页码:- |
| 关键词 | coordination structures heterometallic ions nanocatalysts precious metal nanoclusters Raman spectra |
| ISSN号 | 1616-301X |
| 英文摘要 | Precious metal intermetallic nanoclusters (IMNCs) are promising nanocatalysts for practical industrial applications. However, to date, the preparation of these nanoclusters has been restricted to harsh conditions, and only succeeds for a limited number of elements. This study developed a simple and efficient strategy that enables the synthesis of supported IMNCs under ambient conditions via inorganometallic coordination chemistry, specifically, by donating the Cl- ligand, a noble metal chloride (MClab-) forms a heterobimetallic ion (MxFeyClzn-) with the coordination-unsaturated FeCl3. Upon reduction, the ordered heterobimetallic ions are simultaneously transformed into IMNCs and embedded into gamma-Fe2O3 nanosheets, which form from excess FeCl3. In addition to providing convincing spectral evidence for the structure of the heterobimetallic ions, magnetic measurements, atomic-resolution electron microscopy, X-ray absorption spectroscopy, and Fourier transform infrared spectroscopy of chemisorbed CO collectively confirm the successful preparation of the L1(0)-phased Pd3Fe IMNCs. Furthermore, this versatile method can be extended to synthesize other IMNCs, such as AuFe and PtFe, and seems to be applicable to IrFe, RhFe, RuFe, and MCo. When utilized as a heterogeneous catalyst in a Heck coupling reaction, the prepared Pd3Fe IMNCs display satisfactory activity and stability, highlighting their potential applications as advantageous catalysts. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/42555]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 作者单位 | 1.Beijing Ctr Dis Prevent & Control, Beijing 100013, Peoples R China 2.Chinese Acad Sci, State Key Lab Environm Chem & Ecotoxicol, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China 3.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Rui,Chen, Yanan,Zhao, Huachao,et al. Ligand-Sharing-Mediated Synthesis of Intermetallic FeM Clusters Embedded in Ultrathin gamma-Fe2O3 Nanosheets[J]. ADVANCED FUNCTIONAL MATERIALS,2020,30(5):-. |
| APA | Liu, Rui.,Chen, Yanan.,Zhao, Huachao.,Sun, Jiefang.,He, Zuoliang.,...&Jiang, Guibin.(2020).Ligand-Sharing-Mediated Synthesis of Intermetallic FeM Clusters Embedded in Ultrathin gamma-Fe2O3 Nanosheets.ADVANCED FUNCTIONAL MATERIALS,30(5),-. |
| MLA | Liu, Rui,et al."Ligand-Sharing-Mediated Synthesis of Intermetallic FeM Clusters Embedded in Ultrathin gamma-Fe2O3 Nanosheets".ADVANCED FUNCTIONAL MATERIALS 30.5(2020):-. |
入库方式： OAI收割
来源：生态环境研究中心
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。