Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils
文献类型：期刊论文
| 作者 | Liu, Huan; Gao, Wei2,3 ; Tian, Yong; Wang, Yongmei; Liu, Aifeng; Zhang, Jianqing4; Jiang, Yousheng4; Zhao, Zongshan; Cai, Yaqi1; Jiang, Guibin1
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| 刊名 | TALANTA
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| 出版日期 | 2019-08-01 |
| 卷号 | 200页码:373-377 |
| 关键词 | Thermal decomposition Tandem mass spectrometry Tetrabromobisphenol A bis(allyl ether) Rapid quantitative analysis |
| ISSN号 | 0039-9140 |
| 英文摘要 | Rapidly and sensitively determining trace levels of contaminants with poor ionization in complex matrices is a great challenge for mass spectrometry analysis. In this work, a thermal decomposition tandem mass spectrometry (TD-MS/MS) method is developed for fast detecting tetrabromobisphenol A bis(allyl ether) (TBBPA-BAE) in soils. Typically, TBBPA-BAE solution in a capillary is decomposed and ionized under heating, then sprayed into the mass spectrometer for MS analysis. Upon optimization, one high abundant ion of m/z 542.75 from TBBPA-BAE by debromination is detected during heating process. By collision-induced dissociation, the ion is fragmented to release the characteristic ion of m/z 501.72, which is used as the target quantitative ion. Each test can be finished within 3 min. A linear range of 0.1-100 mu g L-1 limit of detection (LOD, S/N = 3, n = 9) of 0.015 mu g L-1, and relative standard deviation of 8.6% (c = 0.1 mu g L-1, n = 5) are achieved. The fast and sensitive performance of the developed method for analyzing TBBPA-BAE in soils presents its great potential for studying trace levels of TBBPA derivative contaminants. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/42607]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 作者单位 | 1.Shenzhen Ctr Dis Control & Prevent, Shenzhen 518055, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Shandong, Peoples R China 3.Northeastern Univ, Res Ctr Analyt Sci, Coll Sci, Shenyang 110819, Liaoning, Peoples R China 4.Northeastern Univ, Dept Chem, Coll Sci, Shenyang 110819, Liaoning, Peoples R China 5.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Huan,Gao, Wei,Tian, Yong,et al. Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils[J]. TALANTA,2019,200:373-377. |
| APA | Liu, Huan.,Gao, Wei.,Tian, Yong.,Wang, Yongmei.,Liu, Aifeng.,...&Jiang, Guibin.(2019).Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils.TALANTA,200,373-377. |
| MLA | Liu, Huan,et al."Thermal decomposition tandem mass spectrometry for rapid detection of tetrabromobisphenol A bis(allyl ether) in soils".TALANTA 200(2019):373-377. |
入库方式： OAI收割
来源：生态环境研究中心
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