中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Emerging aromatic secondary amine contaminants and related derivatives in various dust matrices in China

文献类型:期刊论文

作者Liu, Runzeng; Li, Yiling; Lin, Yongfeng; Ruan, Ting; Jiang, Guibin
刊名ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
出版日期2019-04-15
卷号170页码:657-663
关键词Aromatic secondary amines Substituted diphenylamines Substituted p-phenylenediamines Derivatives Estimated daily intake
ISSN号0147-6513
英文摘要Aromatic secondary amines (Ar-SAs), constituted of several analogues with varied substitutions in molecular structure, are among the most frequently used anthropogenic antioxidants. Despite the reported toxicity effects, little information is available on their environmental contamination, except for few particular congeners such as diphenylamine. In this study, the occurrence of two kinds of Ar-SAs, substituted diphenylamines (S-DPAs) and novel substituted p-phenylenediamines (S-PPDs), was investigated in dust samples collected from outdoor rubber playgrounds and residential houses. Seven S-DPAs (GM: 102 ng/g) and two S-PPDs (GM: 20.9 ng/g) were detected in indoor dust. Significantly higher concentrations of S-DPAs (GM: 422 ng/g) and S-PPDs (GM: 31.6 ng/g) were observed in playground dust (p < 0.05). Different dominant Ar-SA congeners were found for indoor dust (low molecular weight Ar-SAs) and playground dust (high molecular weight Ar-SAs), indicating varied sources of Ar-SAs for different dust matrices. Apart from these parent chemicals, three diphenylamine derivatives, including N-nitrosodiphenylamine, 2-nitrodiphenylamine, and 4-nitrodiphenylamine, were also confirmed in indoor dust (GM: 35.7 ng/g) and playground dust (GM: 7.88 ng/g). A preliminary estimated daily intake calculation via dust ingestion indicated no immediate health risk to Chinese population. To our knowledge, this is the first report on the occurrence of a wide range of Ar-SAs and related derivates in dust matrices.
源URL[http://ir.rcees.ac.cn/handle/311016/42937]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
作者单位1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Liu, Runzeng,Li, Yiling,Lin, Yongfeng,et al. Emerging aromatic secondary amine contaminants and related derivatives in various dust matrices in China[J]. ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY,2019,170:657-663.
APA Liu, Runzeng,Li, Yiling,Lin, Yongfeng,Ruan, Ting,&Jiang, Guibin.(2019).Emerging aromatic secondary amine contaminants and related derivatives in various dust matrices in China.ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY,170,657-663.
MLA Liu, Runzeng,et al."Emerging aromatic secondary amine contaminants and related derivatives in various dust matrices in China".ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY 170(2019):657-663.

入库方式: OAI收割

来源:生态环境研究中心

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