Oxygen-enriched tubular carbon for efficient solar steam generation
文献类型：期刊论文
| 作者 | Li, Z; Ma, WQ; Xu, JJ; Qian, M; Bi, H; Zhao, W; Lv, ZR; Huang, FQ |
| 刊名 | CARBON
 |
| 出版日期 | 2020-12-10 |
| 页码 | 256 |
| ISSN号 | 0008-6223 |
| DOI | 10.1016/j.carbon.2020.08.039 |
| 文献子类 | Article |
| 英文摘要 | Carbon materials with excellent light-harvesting capacity are promising light absorbers for solar-thermal conversion. However, developing advanced carbon materials with tailored morphology and properties that are suitable for solar steam generation remains challenging. Herein, we have successfully synthesized oxygen-enriched tubular carbon with uniform hollow architecture and some defective structure by pyrolysis of a coordination complex (PEG-CaCl2 precursor). Briefly, PEG molecules can promote the anisotropic growth of CaCl2 nanorods during pyrolysis through coordination interaction (Ca-O), and simultaneously serve as the carbon and oxygen sources for in-situ growth of self-doped tubular carbon using the as-formed nanorods as ideal templates. The resulting tubular carbon with one-dimensional hollow structure, possesses a large specific surface area (613 m(2) g(-1)) for light absorption, low thermal conductivity (0.0474 W m(-1) K-1) for heat localization, and abundant hydrophilic oxygen-containing groups (8.62 at.% oxygen) for efficient water delivery. Thus, the self-floating photothermal membrane based on the tubular carbon, fabricated by the addition of agar binder, exhibits broadband light absorption (96%) and achieves a high evaporation efficiency of 91.3% under one sun illumination. This work provides a new insight to design and synthesize functionalized carbon with controlled morphology and the desired structure for potential application in solar steam generation. (C) 2020 Published by Elsevier Ltd. |
| WOS关键词 | GRAPHENE ; POLYMER ; WATER ; CONVERSION ; NANOWIRES ; PRECURSOR ; MEMBRANE ; ABSORBER ; CALCIUM ; ROUTE |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27592]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Li, Z,Ma, WQ,Xu, JJ,et al. Oxygen-enriched tubular carbon for efficient solar steam generation[J]. CARBON,2020:256. |
| APA | Li, Z.,Ma, WQ.,Xu, JJ.,Qian, M.,Bi, H.,...&Huang, FQ.(2020).Oxygen-enriched tubular carbon for efficient solar steam generation.CARBON,256. |
| MLA | Li, Z,et al."Oxygen-enriched tubular carbon for efficient solar steam generation".CARBON (2020):256. |
入库方式： OAI收割
来源：上海硅酸盐研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。