Defects and microstructure of highly conducting Al-doped ZnO ceramics obtained via spark plasma sintering
文献类型:期刊论文
作者 | Chen, HX; Sun, QY; Tian, T; Zheng, LY; Barre, M; Monot-Laffez, I; Makowska-Janusik, M; Li, GR; Kassiba, AH |
刊名 | JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
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出版日期 | 2020-12-01 |
期号 | 15页码:5529 |
ISSN号 | 0955-2219 |
DOI | 10.1016/j.jeurceramsoc.2020.06.030 |
文献子类 | Article |
英文摘要 | Al-doped ZnO ceramics were sintered by conventional sintering method and spark plasma sintering (SPS) respectively. Electrical properties and microstructure have been investigated by various measurements. The samples sintered via SPS exhibit a huge electrical conductivity, up to 3.0 x 10(5) S/m at room temperature, which was much higher than that of the sample sintered via the conventional sintering. Structural and morphorlogical characterizations pointed out that the further incorporation of Al ions and the absence of a secondary phase, contribute to the increase of the carrier concentration. Raman spectroscopy revealed the occurrence of structural distortions and a disorder induced by Al doping. Photoluminescence spectra were interpreted by different electronic active defects such as the defect complexes (Al-Zn-Zn-i) which play a key for the high electrical conductivity. Thus, SPS and Al doping modified the microstructure and the concentration of the electronic active defects to ensure high electrical conductivities in doped ZnO-based ceramics. |
WOS关键词 | THERMOELECTRIC PROPERTIES ; ELECTRICAL-CONDUCTIVITY ; OPTICAL-PROPERTIES ; GREEN EMISSION ; NANOPARTICLES ; LUMINESCENCE ; TEMPERATURE ; ATMOSPHERE ; ABSORPTION |
WOS研究方向 | Materials Science |
语种 | 英语 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.sic.ac.cn/handle/331005/27603] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
推荐引用方式 GB/T 7714 | Chen, HX,Sun, QY,Tian, T,et al. Defects and microstructure of highly conducting Al-doped ZnO ceramics obtained via spark plasma sintering[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,2020(15):5529. |
APA | Chen, HX.,Sun, QY.,Tian, T.,Zheng, LY.,Barre, M.,...&Kassiba, AH.(2020).Defects and microstructure of highly conducting Al-doped ZnO ceramics obtained via spark plasma sintering.JOURNAL OF THE EUROPEAN CERAMIC SOCIETY(15),5529. |
MLA | Chen, HX,et al."Defects and microstructure of highly conducting Al-doped ZnO ceramics obtained via spark plasma sintering".JOURNAL OF THE EUROPEAN CERAMIC SOCIETY .15(2020):5529. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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