Ultrathin Aramid/COF Heterolayered Membrane for Solid-State Li-Metal Batteries
文献类型：期刊论文
| 作者 | Sun, WL; Zhang, JS; Xie, ML; Lu, DR; Zhao, Z; Li, YQ; Cheng, ZY; Zhang, SJ; Chen, HW |
| 刊名 | NANO LETTERS
 |
| 出版日期 | 2020-11-11 |
| 期号 | 11页码:8120 |
| ISSN号 | 1530-6984 |
| DOI | 10.1021/acs.nanolett.0c03133 |
| 文献子类 | Article |
| 英文摘要 | Ultrathin, ultrastrong, and highly conductive solid-state polymer-based composite electrolytes have long been exploited for the next-generation lithium-based batteries. In particular, the lightweight membranes that are less than tens of microns are strongly desired, aiming to maximize the energy densities of solidstate batteries. However, building such ideal membranes are challenging when using traditional materials and fabrication technologies. Here we reported a 7.1 mu m thick heterolayered Kevlar/covalent organic framework (COF) composite membrane fabricated via a bottom-up spin layer-by-layer assembly technology that allows for precise control over the structure and thickness of the obtained membrane. Much stronger chemical/mechanical interactions between cross-linked Kevlar and conductive 2D-COF building blocks were designed, resulting in a highly strong and Li+ conductive (1.62 x 10(-4) S cm(-1) at 30 degrees C and 4.6 x 10(-4) S cm(-1) at 70 degrees C) electrolyte membrane that can prevent solid-state batteries from short-circuiting after over 500 h of cycling. All-solid- state lithium batteries using this membrane enable a significantly improved energy density. |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27626]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Sun, WL,Zhang, JS,Xie, ML,et al. Ultrathin Aramid/COF Heterolayered Membrane for Solid-State Li-Metal Batteries[J]. NANO LETTERS,2020(11):8120. |
| APA | Sun, WL.,Zhang, JS.,Xie, ML.,Lu, DR.,Zhao, Z.,...&Chen, HW.(2020).Ultrathin Aramid/COF Heterolayered Membrane for Solid-State Li-Metal Batteries.NANO LETTERS(11),8120. |
| MLA | Sun, WL,et al."Ultrathin Aramid/COF Heterolayered Membrane for Solid-State Li-Metal Batteries".NANO LETTERS .11(2020):8120. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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