Improved temperature sensing performance based on Stark sublevels of Er3+/Yb3+ co-doped tungstate-molybdate up-conversion phosphors
文献类型：期刊论文
| 作者 | Zhao, Y; Wang, XS; Hu, R; Zhang, Y; Li, YX; Yao, X |
| 刊名 | MATERIALS RESEARCH BULLETIN
 |
| 出版日期 | 2020-11-01 |
| ISSN号 | 0025-5408 |
| DOI | 10.1016/j.materresbull.2020.110959 |
| 文献子类 | Article |
| 英文摘要 | Herein, a new up-conversion temperature sensor of LiCaLa(W0.1Mo0.9O4)(3):0.04 Er3+/0.1Yb(3+) phosphors that exhibit strong luminescence intensity, improved and good repeatable temperature sensing performance and stability, was reported for the first time. All samples show typical tetragonal scheelite structures and exhibit typical up-conversion luminescence. Three distinct emission bands correspond to two strong green (H-2(11/2)/S-4(3/2) -> I-4(15/2)) and a weak red (F-4(9/2) -> I-4(15/2)) bands, respectively. WO42- and MoO42- with similar properties can be replaced with each other to improve the crystal field and ultimately improve the luminescence efficiency. Interestingly, the fluorescence intensity ratios of the two sublevels (S-4(3/2(1)) and S-4(3/2(2))) and H-2(11/2) increase with the increase of temperature, indicating the improvement of temperature sensing performance. The S-A-(ma)x are 0.0134 K-1 and 0.0104 K-1, and S-R(-)ma(x) are 0.0434 K-1 and 0.0548 K-1 for H-2(11/2)/S-4(3/2(1)) and H-2(11/2)/S-4(3/2(2)), respectively. Therefore, the tungstate-molybdate up-conversion luminescence materials has a potential application prospect of optical temperature sensor. |
| WOS关键词 | FLUORESCENCE INTENSITY RATIO ; ENERGY-TRANSFER ; LUMINESCENCE ; THERMOMETRY ; BEHAVIOR ; COLOR ; DEPENDENCE ; EMISSION ; CAWO4 ; SM3+ |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27662]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Zhao, Y,Wang, XS,Hu, R,et al. Improved temperature sensing performance based on Stark sublevels of Er3+/Yb3+ co-doped tungstate-molybdate up-conversion phosphors[J]. MATERIALS RESEARCH BULLETIN,2020. |
| APA | Zhao, Y,Wang, XS,Hu, R,Zhang, Y,Li, YX,&Yao, X.(2020).Improved temperature sensing performance based on Stark sublevels of Er3+/Yb3+ co-doped tungstate-molybdate up-conversion phosphors.MATERIALS RESEARCH BULLETIN. |
| MLA | Zhao, Y,et al."Improved temperature sensing performance based on Stark sublevels of Er3+/Yb3+ co-doped tungstate-molybdate up-conversion phosphors".MATERIALS RESEARCH BULLETIN (2020). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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