Li1.5Al0.5Ge1.5(PO4)(3)Ceramic Based Lithium-Sulfur Batteries with High Cycling Stability Enabled by a Dual Confinement Effect for Polysulfides
文献类型：期刊论文
| 作者 | Wang, Q; Lu, Y; Jin, J; Chen, CH; Wen, ZY |
| 刊名 | CHEMELECTROCHEM
 |
| 出版日期 | 2020-10-01 |
| 期号 | 19页码:4093 |
| ISSN号 | 2196-0216 |
| DOI | 10.1002/celc.202001131 |
| 文献子类 | Article |
| 英文摘要 | Aimed at tackling the shuttle effect in lithium-sulfur (Li-S) batteries, a Li1.5Al0.5Ge1.5(PO4)(3)(LAGP) ceramic is adopted to block the migration of polysulfides. However, the LAGP-based Li-S battery with liquid electrolyte wetting the interfaces still suffers from rapid capacity decay, as polysulfides tend to dissolve into liquid electrolyte and get firmly adsorbed by LAGP. In this work, a dual confinement effect for polysulfides is put forward, enabled by the LAGP ceramic and solvent-in-salt (SIS), wherein the SIS can greatly suppress the dissolution of polysulfides. Owing to the synergistic effect of SIS and LAGP, the semi-solid-state Li-S batteries show superior capacity retention and long cycling life. In particular, at a current density of 0.2 C, the Li-S battery with SIS-modified LAGP ceramic electrolyte delivers a high initial reversible capacity of 1251.7 mAh g(-1)and long cycle life of over 250 cycles with a decay rate of only 0.07 % per cycle. |
| WOS关键词 | HIGH-PERFORMANCE ; SOLID-ELECTROLYTE ; CATHODE ; METAL ; ANODE ; ORGANOSULFIDE ; SPECTROSCOPY ; DISSOLUTION ; INTERLAYER ; INTERFACE |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27712]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Wang, Q,Lu, Y,Jin, J,et al. Li1.5Al0.5Ge1.5(PO4)(3)Ceramic Based Lithium-Sulfur Batteries with High Cycling Stability Enabled by a Dual Confinement Effect for Polysulfides[J]. CHEMELECTROCHEM,2020(19):4093. |
| APA | Wang, Q,Lu, Y,Jin, J,Chen, CH,&Wen, ZY.(2020).Li1.5Al0.5Ge1.5(PO4)(3)Ceramic Based Lithium-Sulfur Batteries with High Cycling Stability Enabled by a Dual Confinement Effect for Polysulfides.CHEMELECTROCHEM(19),4093. |
| MLA | Wang, Q,et al."Li1.5Al0.5Ge1.5(PO4)(3)Ceramic Based Lithium-Sulfur Batteries with High Cycling Stability Enabled by a Dual Confinement Effect for Polysulfides".CHEMELECTROCHEM .19(2020):4093. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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