Intermediate band induced by p-block metalloid antimony in SnS2 for higher solar energy utilization
文献类型：期刊论文
| 作者 | Hu, KY; Gu, YH; Xu, ZA; Wang, D; Liu, XY; Zhao, W; Huang, FQ |
| 刊名 | MATERIALS TODAY COMMUNICATIONS
 |
| 出版日期 | 2020-09-01 |
| ISSN号 | 2352-4928 |
| DOI | 10.1016/j.mtcomm.2020.101333 |
| 文献子类 | Article |
| 英文摘要 | Semiconductors with intermediate bands have attracted tremendous attention due to their superior solar energy utilization. Herein, we propose a simple approach to introduce the intermediate band through substituting tin by p-block metalloid antimony in SnS2. Experimentally, Sn1-xSbxS2 (x up to 0.06) semiconductors possessing an intermediate band were successfully synthesized through solid state reactions. After antimony doping, two absorption edges appear at 2.31 eV and 1.63 eV in the visible light region, and one absorption shoulder starting at 0.68 eV emerges in the infrared region, as observed from the UV-vis-NIR absorption spectra. These typical intermediate band absorption features are consistent with our first principles calculations. The state of the intermediate band of Sn1-xSbxS2 is mainly composed of the Sb-5s orbital from maximally-localized Wannier function analysis. Owing to the antimony intermediate band extending the solar absorption range, Sn1-xSbxS2 semiconductors exhibit a higher utilization of solar energy compared with pristine SnS2. |
| WOS关键词 | 2-DIMENSIONAL SNS2 ; DOPED SNS2 ; PHOTOCATALYTIC ACTIVITY ; OPTICAL-PROPERTIES ; PERFORMANCE ; NANOSHEETS ; ABSORBERS ; DRIVEN |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27780]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Hu, KY,Gu, YH,Xu, ZA,et al. Intermediate band induced by p-block metalloid antimony in SnS2 for higher solar energy utilization[J]. MATERIALS TODAY COMMUNICATIONS,2020. |
| APA | Hu, KY.,Gu, YH.,Xu, ZA.,Wang, D.,Liu, XY.,...&Huang, FQ.(2020).Intermediate band induced by p-block metalloid antimony in SnS2 for higher solar energy utilization.MATERIALS TODAY COMMUNICATIONS. |
| MLA | Hu, KY,et al."Intermediate band induced by p-block metalloid antimony in SnS2 for higher solar energy utilization".MATERIALS TODAY COMMUNICATIONS (2020). |
入库方式： OAI收割
来源：上海硅酸盐研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。