中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synergistic Effect of Al3+/Li+-Based All-Solid-State Electrochromic Devices with Robust Performance

文献类型:期刊论文

作者Zhu, Y; Xie, LL; Chang, TC; Huang, AB; Jin, P; Bao, SH
刊名ACS APPLIED ELECTRONIC MATERIALS
出版日期2020-07-28
期号7页码:2171
ISSN号2637-6113
DOI10.1021/acsaelm.0c00376
文献子类Article
英文摘要In the electrochromic devices (ECDs), the commonly employed active ions are monovalent ions, such as Li+, for the advantages of small ionic radius and high ion transportation. However, monovalent ions still show several disadvantages, including poor chemical stability, expensive costs, difficult waste disposal, and so on. Here, we proposed a synergistic Al3+/Li+ all-solid-state electrochromic device prepared by magnetron sputtering, which extracts the essence of trivalent ion Al3+ and monovalent ion Li+ and remove their dross. It has been demonstrated that the introduction of Li+ ions can activate the Al3+ ions in the solid electrolyte, and both Al3+ and Li+ ions can induce the electrochromic reaction in the all-solid-state ECDs. The synergistic effect of Al3+/Li+ can promote the performance of ECDs, which includes high optical contrast of 56%, fast coloration time of 9.73 s and bleaching time of 2.98 s, and relatively high coloration efficiency of 62.81 cm(2).C-1. Our findings are expected to provide a novel strategy for the utilization of trivalent ions in all-solid-state electrochromic devices.
WOS关键词IONIC-CONDUCTIVITY ; ALUMINUM SILICATE ; ELECTROLYTE ; FILM ; WO3 ; STABILITY ; TRANSPORT ; GELATIN ; DISPLAY ; BLUE
WOS研究方向Engineering ; Materials Science
语种英语
出版者AMER CHEMICAL SOC
源URL[http://ir.sic.ac.cn/handle/331005/27883]  
专题中国科学院上海硅酸盐研究所
推荐引用方式
GB/T 7714
Zhu, Y,Xie, LL,Chang, TC,et al. Synergistic Effect of Al3+/Li+-Based All-Solid-State Electrochromic Devices with Robust Performance[J]. ACS APPLIED ELECTRONIC MATERIALS,2020(7):2171.
APA Zhu, Y,Xie, LL,Chang, TC,Huang, AB,Jin, P,&Bao, SH.(2020).Synergistic Effect of Al3+/Li+-Based All-Solid-State Electrochromic Devices with Robust Performance.ACS APPLIED ELECTRONIC MATERIALS(7),2171.
MLA Zhu, Y,et al."Synergistic Effect of Al3+/Li+-Based All-Solid-State Electrochromic Devices with Robust Performance".ACS APPLIED ELECTRONIC MATERIALS .7(2020):2171.

入库方式: OAI收割

来源:上海硅酸盐研究所

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