Sr4Pb1.5Sb5O5Se8: a new mid-infrared nonlinear optical material with a moderate SHG response
文献类型：期刊论文
| 作者 | Wang, Y; Luo, MJ; Zhao, P; Che, XL; Cao, YZ; Huang, FQ |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2020-05-28 |
| 期号 | 20页码:3526 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/d0ce00084a |
| 文献子类 | Article |
| 英文摘要 | A new mid-infrared nonlinear optical oxyselenide compound, Sr4Pb1.5Sb5O5Se8, was successfully synthesized by traditional solid-state reaction. It crystallizes in the noncentrosymmetric space group Cm (No. 8) of the monoclinic system. The crystal structure is composed of edge-sharing quasi-2D (2)(infinity)[Pb1.5Sb3-Se-8](4-) zigzag layers with Sr2+ ions and anionic (1)(infinity)[SbO2.5](2-) pseudo-chains separating the adjacent layers. The compound has good thermal stability up to approximately 1000 K which is beneficial for nonlinear optical applications. The sharp down signal of the second harmonic generation (SHG) response measured with a 2.09 mu m laser in the reflection mode reveals its nonlinear optical properties. The new compound Sr4Pb1.5Sb5O5Se8 provides some guidance to design new mid-infrared nonlinear optical materials. |
| WOS关键词 | QUATERNARY CHALCOGENIDES ; 2ND-HARMONIC GENERATION ; METAL CHALCOGENIDES ; CHALCOHALIDES ; SULFIDES ; SERIES ; MIDDLE ; SE ; RB ; GE |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.sic.ac.cn/handle/331005/28041]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Wang, Y,Luo, MJ,Zhao, P,et al. Sr4Pb1.5Sb5O5Se8: a new mid-infrared nonlinear optical material with a moderate SHG response[J]. CRYSTENGCOMM,2020(20):3526. |
| APA | Wang, Y,Luo, MJ,Zhao, P,Che, XL,Cao, YZ,&Huang, FQ.(2020).Sr4Pb1.5Sb5O5Se8: a new mid-infrared nonlinear optical material with a moderate SHG response.CRYSTENGCOMM(20),3526. |
| MLA | Wang, Y,et al."Sr4Pb1.5Sb5O5Se8: a new mid-infrared nonlinear optical material with a moderate SHG response".CRYSTENGCOMM .20(2020):3526. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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