Constructing Hierarchical Porous Carbon of High-Performance Capacitance through a Two-Step Nitrogen-Fixation Method
文献类型：期刊论文
| 作者 | Qi, XH; Xu, F; Sun, P; Lin, TQ; Huang, FQ |
| 刊名 | ENERGY TECHNOLOGY
 |
| 出版日期 | 2020-07-01 |
| 期号 | 7 |
| ISSN号 | 2194-4288 |
| DOI | 10.1002/ente.202000107 |
| 文献子类 | Article |
| 英文摘要 | Highly conductive and nitrogen-rich carbon materials have broad application prospects in energy storage, yet they are somehow contradictory because good conductivity requires high-temperature heat treatment, which decomposes most nitrogen species. Herein, a novel approach to synthesize a nitrogen-rich and highly conductive carbon material with extraordinary capacitance through a two-step nitrogen-fixation sol-gel method is reported. The process benefits from the coordination of Zn2+ with nitrogen atoms in the precursor sol and the stabilizing bonding between silicon and nitrogen during high-temperature chemical vapor deposition. The final product shows a high nitrogen content of 5.6 at%, a hierarchical porous structure with a high specific surface area (1610 m(2) g(-1)), and an extraordinary conductivity (23 S cm(-1)), which enables an impressive capacitance of 380 F g(-1). This nitrogen-fixing method starting with a composite sol-gel may offer a reliable route to the preparation of high-performance supercapacitor electrode materials. |
| WOS关键词 | MESOPOROUS CARBON ; KOH ACTIVATION ; SUPERCAPACITORS ; WASTE ; ZN |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.sic.ac.cn/handle/331005/28042]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Qi, XH,Xu, F,Sun, P,et al. Constructing Hierarchical Porous Carbon of High-Performance Capacitance through a Two-Step Nitrogen-Fixation Method[J]. ENERGY TECHNOLOGY,2020(7). |
| APA | Qi, XH,Xu, F,Sun, P,Lin, TQ,&Huang, FQ.(2020).Constructing Hierarchical Porous Carbon of High-Performance Capacitance through a Two-Step Nitrogen-Fixation Method.ENERGY TECHNOLOGY(7). |
| MLA | Qi, XH,et al."Constructing Hierarchical Porous Carbon of High-Performance Capacitance through a Two-Step Nitrogen-Fixation Method".ENERGY TECHNOLOGY .7(2020). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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