Electron Configuration Modulation of Nickel Single Atoms for Elevated Photocatalytic Hydrogen Evolution
文献类型：期刊论文
| 作者 | Jin, XX; Wang, RY; Zhang, LX; Si, R; Shen, M; Wang, M; Tian, JJ; Shi, JL |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2020-04-20 |
| 期号 | 17页码:6827 |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201914565 |
| 文献子类 | Article |
| 英文摘要 | The emerging metal single-atom catalyst has aroused extensive attention in multiple fields, such as clean energy, environmental protection, and biomedicine. Unfortunately, though it has been shown to be highly active, the origins of the activity of the single-atom sites remain unrevealed to date owing to the lack of deep insight on electronic level. Now, partially oxidized Ni single-atom sites were constructed in polymeric carbon nitride (CN), which elevates the photocatalytic performance by over 30-fold. The 3d orbital of the partially oxidized Ni single-atom sites is filled with unpaired d-electrons, which are ready to be excited under irradiation. Such an electron configuration results in elevated light response, conductivity, charge separation, and mobility of the photocatalyst concurrently, thus largely augmenting the photocatalytic performance. |
| WOS关键词 | CARBON NITRIDE ; WATER ; CATALYSTS ; H-2 |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.sic.ac.cn/handle/331005/28130]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Jin, XX,Wang, RY,Zhang, LX,et al. Electron Configuration Modulation of Nickel Single Atoms for Elevated Photocatalytic Hydrogen Evolution[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020(17):6827. |
| APA | Jin, XX.,Wang, RY.,Zhang, LX.,Si, R.,Shen, M.,...&Shi, JL.(2020).Electron Configuration Modulation of Nickel Single Atoms for Elevated Photocatalytic Hydrogen Evolution.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(17),6827. |
| MLA | Jin, XX,et al."Electron Configuration Modulation of Nickel Single Atoms for Elevated Photocatalytic Hydrogen Evolution".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION .17(2020):6827. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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