Carbon fiber micron film guided uniform plating/stripping of metals: A universal approach for highly stable metal batteries
文献类型：期刊论文
| 作者 | Du, YX; Liu, CW; Liu, YZ; Han, Q; Chi, XW; Liu, Y |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2020-04-10 |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2020.135867 |
| 文献子类 | Article |
| 英文摘要 | Rechargeable metal batteries are desirable for next-generation high specific energy electrochemical energy storage systems. However, low coulombic efficiency and severe dendrite growth during the stripping/plating of metals (e.g. Li, Na, Zn and etc.) considerably hinder their practical applications. To address the above issues, in this work, a facile, versatile, and scalable approach by means of spray depositing carbon fiber micron film (CFMF) onto metals is developed. The porous, uniform, and highly conductive CFMF firmly attached to metal surface with a scaffold structure is found to effectively guide the uniform plating/stripping of both the Zn metal in aqueous electrolytes and the Li metal in organic electrolytes, thus enabling much higher efficiencies of Zn (98.4%) and Li (99.7%) for the 100th cycle on the CFMF-modified current collectors than those of bare current collectors. And the so far record high cycling stability for the symmetric cells using CFMF/Zn (2500 h) and CFMF/Li (1000 h) electrodes is achieved at 1 mA cm(-)(2) and 4 mA cm(-)(2), respectively. Benefiting from the delicately designed CFMF-modified Zn or Li metal anodes, the full cells of Zn-MnO2 and Li-LiMn2O4 are rendered excellent rate capability and significantly extended cycle life. (C) 2020 Elsevier Ltd. All rights reserved. |
| WOS关键词 | LITHIUM DEPOSITION ; CURRENT COLLECTOR ; LONG-LIFE ; ION ; ANODE ; OXIDE |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.sic.ac.cn/handle/331005/28149]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Du, YX,Liu, CW,Liu, YZ,et al. Carbon fiber micron film guided uniform plating/stripping of metals: A universal approach for highly stable metal batteries[J]. ELECTROCHIMICA ACTA,2020. |
| APA | Du, YX,Liu, CW,Liu, YZ,Han, Q,Chi, XW,&Liu, Y.(2020).Carbon fiber micron film guided uniform plating/stripping of metals: A universal approach for highly stable metal batteries.ELECTROCHIMICA ACTA. |
| MLA | Du, YX,et al."Carbon fiber micron film guided uniform plating/stripping of metals: A universal approach for highly stable metal batteries".ELECTROCHIMICA ACTA (2020). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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