Lithium dendrite-free and fast-charging for high voltage nickel-rich lithium metal batteries enabled by bifunctional sulfone-containing electrolyte additives
文献类型：期刊论文
| 作者 | Zhang, XW; Wu, QP; Guan, X; Cao, FH; Li, CL; Xu, J |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2020-03-15 |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2020.227833 |
| 文献子类 | Article |
| 英文摘要 | Lithium dendrites limit the application of lithium metal as anode, and poor interfacial stability restricts the nickel-rich lithium nickel cobalt manganese oxides as cathode. Herein, diphenyl sulfone (DPS) and bis(4-florophenyl) sulfone (BFS) are proposed as bifunctional electrolyte additives. In the Li parallel to LI symmetrical half-batteries, with 0.5 wt % DPS, high cycle stability for 360 h at the current density of 1 mA cm(-2) is realized by forming a dense and smooth LiF-rich solid electrolyte interphase (SEI). In the Li parallel to LiNi0.8Mn0.1Co0.1O2 (NMC811) battery, from the long-term cycle tests at 5C after 500 cycles, the capacity retention loss of 0.05% per cycle is found by addition of 0.5 wt% DPS, which is much lower than that with 0.5 wt% of BFS (0.08%) and no additives (0.16%). Proper content of LIP, Li2SO3 and ROSO2Li caused by DPS are beneficial to form a stable solid electrolyte interphase film for the Li parallel to NMC batteries, which facilitates lithium ion transport, and inhibits electron transfer. Therefore, Li parallel to NMC batteries with additives exhibit longer cycle life, higher capacity retention and better fast charging performance than that without any additive. |
| WOS关键词 | ION BATTERIES ; CATHODE MATERIALS ; VINYLENE CARBONATE ; PERFORMANCE ; OXIDES ; FILM |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| 源URL | [http://ir.sic.ac.cn/handle/331005/28226]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, XW,Wu, QP,Guan, X,et al. Lithium dendrite-free and fast-charging for high voltage nickel-rich lithium metal batteries enabled by bifunctional sulfone-containing electrolyte additives[J]. JOURNAL OF POWER SOURCES,2020. |
| APA | Zhang, XW,Wu, QP,Guan, X,Cao, FH,Li, CL,&Xu, J.(2020).Lithium dendrite-free and fast-charging for high voltage nickel-rich lithium metal batteries enabled by bifunctional sulfone-containing electrolyte additives.JOURNAL OF POWER SOURCES. |
| MLA | Zhang, XW,et al."Lithium dendrite-free and fast-charging for high voltage nickel-rich lithium metal batteries enabled by bifunctional sulfone-containing electrolyte additives".JOURNAL OF POWER SOURCES (2020). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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