Surface coating of LiMn2O4 cathodes with garnet electrolytes for improving cycling stability of solid lithium batteries
文献类型:期刊论文
作者 | Bi, ZJ; Zhao, N; Ma, LN; Shi, C; Fu, ZQ; Xu, FF; Guo, XX |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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出版日期 | 2020-02-28 |
期号 | 8页码:4252 |
ISSN号 | 2050-7488 |
DOI | 10.1039/c9ta11203k |
文献子类 | Article |
英文摘要 | Spinel lithium manganese oxide (LiMn2O4) is an attractive cathode material, and has advantages including low cost, environmental friendliness, and easy synthesis as well as shortcomings including inferior cycling stability at elevated temperatures above 55 degrees C. In this work, LiMn2O4 cathodes are coated with Li6.375La3Zr1.375Nb0.625O12 (LLZNO) electrolytes. Such cathodes in solid batteries consisting of garnet ceramic electrolytes and Li anodes exhibit a discharge capacity retention of 81.3% after 100 cycles at 0.2C and 55 degrees C. This superior performance is attributed to the unique interface between LiMn2O4 and LLZNO, which is not only ionically conductive but also helpful to suppress Mn reactivity. |
WOS关键词 | ATOMIC LAYER DEPOSITION ; ELECTROCHEMICAL PERFORMANCE ; ELEVATED-TEMPERATURE ; RATE CAPABILITY ; COATED LIMN2O4 ; STATE LITHIUM ; SPINEL ; LINI0.5MN1.5O4 ; CONDUCTIVITY ; INTERFACES |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
源URL | [http://ir.sic.ac.cn/handle/331005/28280] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
推荐引用方式 GB/T 7714 | Bi, ZJ,Zhao, N,Ma, LN,et al. Surface coating of LiMn2O4 cathodes with garnet electrolytes for improving cycling stability of solid lithium batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2020(8):4252. |
APA | Bi, ZJ.,Zhao, N.,Ma, LN.,Shi, C.,Fu, ZQ.,...&Guo, XX.(2020).Surface coating of LiMn2O4 cathodes with garnet electrolytes for improving cycling stability of solid lithium batteries.JOURNAL OF MATERIALS CHEMISTRY A(8),4252. |
MLA | Bi, ZJ,et al."Surface coating of LiMn2O4 cathodes with garnet electrolytes for improving cycling stability of solid lithium batteries".JOURNAL OF MATERIALS CHEMISTRY A .8(2020):4252. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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