Spherical Sacrificial ZnO Template-Derived Hybrid Ni/Co3O4 Cubes as Efficient Bifunctional Electrocatalyst for Overall Water Splitting
文献类型：期刊论文
| 作者 | Riaz, MS; Zhao, SW; Dong, CL; Iqbal, MJ; Zhao, YT; Huang, FQ |
| 刊名 | ENERGY TECHNOLOGY
 |
| 出版日期 | 2020-05-01 |
| 期号 | 5 |
| ISSN号 | 2194-4288 |
| DOI | 10.1002/ente.201901310 |
| 文献子类 | Article |
| 英文摘要 | Heterostructure transition metal derivatives have been extensively studied in electrocatalysis, but most of the hybrid samples are on nanoscale with low stability and tap density. ZnO microspheres are applied as a sacrificial template, followed by alkaline etching and aluminum reduction to construct Ni/Co3O4 microcubes. The porous hybrid microcubes show stirring performance in both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). For HER, it exhibits comparable overpotential of 145 mV at 10 mA cm(-2) as Pt/C (101 mV) and desirable stability. For OER, it outperforms RuO2 with lower overpotential when the current exceeds 17.8 mA cm(-2) and much smaller Tafel slope of 34 mV dec(-1) versus RuO2 (72 mV dec(-1)). The potential activity is assigned to the charge transfer at the heterointerfaces, and the synergic effects of the Ni/Co3O4 phases, which possibly will cast light on the design of microscale bifunctional electrocatalysts. |
| WOS关键词 | OXYGEN EVOLUTION REACTION ; ENERGY-CONVERSION ; HYDROGEN ; NANOCAGE ; STORAGE |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.sic.ac.cn/handle/331005/28357]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Riaz, MS,Zhao, SW,Dong, CL,et al. Spherical Sacrificial ZnO Template-Derived Hybrid Ni/Co3O4 Cubes as Efficient Bifunctional Electrocatalyst for Overall Water Splitting[J]. ENERGY TECHNOLOGY,2020(5). |
| APA | Riaz, MS,Zhao, SW,Dong, CL,Iqbal, MJ,Zhao, YT,&Huang, FQ.(2020).Spherical Sacrificial ZnO Template-Derived Hybrid Ni/Co3O4 Cubes as Efficient Bifunctional Electrocatalyst for Overall Water Splitting.ENERGY TECHNOLOGY(5). |
| MLA | Riaz, MS,et al."Spherical Sacrificial ZnO Template-Derived Hybrid Ni/Co3O4 Cubes as Efficient Bifunctional Electrocatalyst for Overall Water Splitting".ENERGY TECHNOLOGY .5(2020). |
入库方式： OAI收割
来源：上海硅酸盐研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。