Sample pretreatment is an important prerequisite for analyzing complex samples due to the low concentra-
tion of targets and numerous interferences in sample matrix. As a group of emerging absorbents, metal-organic
frameworks (MOFs)-derived porous carbons (MPCs), obtained by high-temperature pyrolysis of MOFs, have been
brought into stage recently due to their intrinsic advantages such as high porosity, permanent nanoscale cavities
and open channels. The morphology of the original MOF precursor is well maintained after calcination produces.
Furthermore, by directly calcinating MOFs comprised of magnetic metal centers (Co, Fe, Ni), magnetic porous
carbon with excellent magnetism and separation efficiency can be fabricated. The uniformly distributed magnetic
metal nanoparticles in the carbon matrix is helpful to reduce the agglomeration problem of magnetic nanoparti-
cles and the porosity of carbon materials inherited from MOFs is beneficial to evaluate the adsorptive property.
So MPCs has been widely used in sample preparation of environmental, biological samples and food matrices. In
this review, we summarize the performances and different process for the preparation of MPCs. Moreover, this
review mainly focuses on providing a detailed discussion about the application of MPCs for extracting analytes
from complex matrix in different sample pretreatment modes such as solid-phase extraction, magnetic solid phase
extraction and solid-phase microextraction. In addition, the efforts recently on the automation of magnetic solid
phase extraction processes by means of MPCs are also described.