Preparation of MOF Film/Aerogel Composite Catalysts via Substrate-Seeding Secondary-Growth for the Oxygen Evolution Reaction and CO2 Cycloaddition
文献类型：期刊论文
| 作者 | Bai, Xiao-Jue; Lu, Xing-Yu; Ju, Ran; Chen, Huan; Shao, Lei; Zhai, Xu; Li, Yu-Nong; Fan, Fu-Qiang; Fu, Yu; Qi, Wei |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2020-11-09 |
| DOI | 10.1002/anie.202012354 |
| 英文摘要 | Substrate-supported metal-organic frameworks (MOFs) films are desired to realize their potential in practical applications. Herein, a novel substrate-seeding secondary-growth strategy is developed to prepare composites of uniform MOFs films on aerogel walls. Briefly, the organic ligand is "pre-seeded" onto the aerogel walls, and then a small amount of metal-ion solution is sprayed onto the prepared aerogel. The sprayed solution diffuses along the aerogel walls to form a continuous thin layer, which confines the nucleation reaction, promoting the formation of uniform MOFs films on the aerogel walls. The whole process is simple in operation, highly efficient, and eco-friendly. The resulting hierarchical MOFs/aerogel composites have abundant accessible active sites and enable excellent mass transfer, which endows the composite with outstanding catalytic activity and stability in both liquid-phase CO2 cycloaddition and electrochemical oxygen evolution reaction (OER) process. |
| WOS记录号 | WOS:000587499300001 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/82364]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Bai, Xiao-Jue,Lu, Xing-Yu,Ju, Ran,et al. Preparation of MOF Film/Aerogel Composite Catalysts via Substrate-Seeding Secondary-Growth for the Oxygen Evolution Reaction and CO2 Cycloaddition[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020. |
| APA | Bai, Xiao-Jue.,Lu, Xing-Yu.,Ju, Ran.,Chen, Huan.,Shao, Lei.,...&Qi, Wei.(2020).Preparation of MOF Film/Aerogel Composite Catalysts via Substrate-Seeding Secondary-Growth for the Oxygen Evolution Reaction and CO2 Cycloaddition.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. |
| MLA | Bai, Xiao-Jue,et al."Preparation of MOF Film/Aerogel Composite Catalysts via Substrate-Seeding Secondary-Growth for the Oxygen Evolution Reaction and CO2 Cycloaddition".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020). |
入库方式： OAI收割
来源：金属研究所
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