Constructing a TiO2/PDA core/shell nanorod array electrode as a highly sensitive and stable photoelectrochemical glucose biosensor
文献类型:期刊论文
作者 | Xu, Wei; Yang, Wenke; Guo, Hongkai; Ge, Lianyuan; Tu, Jinchun; Zhen, Chao |
刊名 | RSC ADVANCES
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出版日期 | 2020-03-10 |
卷号 | 10期号:17页码:10017-10022 |
DOI | 10.1039/c9ra10445c |
英文摘要 | Developing stable PEC glucose biosensors with high sensitivity and low detection limit is highly desirable in the biosensor field. Herein, a highly stable and sensitive enzymatic glucose photoelectrochemical biosensor is rationally designed and fabricated by constructing TiO2/PDA core/shell nanorod arrays. The TiO2 nanorod as the core has the advantages of increasing charge transportation towards interfaces and enhancing the absorption of incident sunlight due to its single-crystal nature and one dimensional array structure. The PDA shell not only induces a rapid charge transfer across the interfaces but also stabilizes the biosensor performance by avoiding the decomposition of enzymes induced by the strong oxidizing holes from the TiO2 core. A remarkable performance with an ultrahigh sensitivity of 57.72 mu A mM(-1) cm(-2), a linear range of 0.2-1.0 mM, a glucose detection limit of 0.0285 mM (S/N = 3) and a high sensitivity of 8.75 mu A mM(-1) cm(-2) in a dynamic range of 1.0-6.0 mM were obtained for the glucose detection. This study might provide a strategy for constructing inorganic/organic core/shell structures with a satisfactory PEC performance. |
WOS记录号 | WOS:000520511800029 |
源URL | [http://ir.imr.ac.cn/handle/321006/83049] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Xu, Wei,Yang, Wenke,Guo, Hongkai,et al. Constructing a TiO2/PDA core/shell nanorod array electrode as a highly sensitive and stable photoelectrochemical glucose biosensor[J]. RSC ADVANCES,2020,10(17):10017-10022. |
APA | Xu, Wei,Yang, Wenke,Guo, Hongkai,Ge, Lianyuan,Tu, Jinchun,&Zhen, Chao.(2020).Constructing a TiO2/PDA core/shell nanorod array electrode as a highly sensitive and stable photoelectrochemical glucose biosensor.RSC ADVANCES,10(17),10017-10022. |
MLA | Xu, Wei,et al."Constructing a TiO2/PDA core/shell nanorod array electrode as a highly sensitive and stable photoelectrochemical glucose biosensor".RSC ADVANCES 10.17(2020):10017-10022. |
入库方式: OAI收割
来源:金属研究所
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