Prediction of viscosity for high-concentrated ternary solution (CH3SO3H + VOSO4 + H2O) in vanadium flow battery
文献类型：期刊论文
| 作者 | Li, Xiangrong; Jiang, Chenglin; Liu, Jianguo; Qin, Ye; Zhang, Zhongyu; Liu, Zaibo; Yang, Jiazhen; Yan, Chuanwei |
| 刊名 | JOURNAL OF MOLECULAR LIQUIDS
 |
| 出版日期 | 2020 |
| 卷号 | 297 |
| DOI | 10.1016/j.molliq.2019.111908 |
| 英文摘要 | In this paper, a model for viscosity of high-concentrated additive (methanesulfonic acid) in vanadium electrolyte is reported. Methanesulfonic acid was evaluated as a possible stabilizing agent for the thermal precipitation of supersaturated V(V) solutions at elevated temperatures. Viscosity (eta) of the ternary solution CH3SO3H + VOSO4 + H2O was measured between the temperatures 283.15 K and 318.15 K under atmospheric pressure. Based on the viscosity, viscosity B-coefficient, activation energy (Delta mu(not equal 0)(0)) and Gibbs free energy of activation (Delta G(not equal)) were further calculated. With the help of these paraments, a semi-empirical predicting function is established to estimate the viscosity of high-concentrated additive, i.e. methanesulfonic acid in vanadium electrolyte. AARD of this semi-empirical method is 0.22%, which demonstrates that viscosity estimation for high-concentrated ternary solution CH3SO3H + VOSO4 + H2O can be achieved. (C) 2019 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000512219100078 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/83256]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Li, Xiangrong,Jiang, Chenglin,Liu, Jianguo,et al. Prediction of viscosity for high-concentrated ternary solution (CH3SO3H + VOSO4 + H2O) in vanadium flow battery[J]. JOURNAL OF MOLECULAR LIQUIDS,2020,297. |
| APA | Li, Xiangrong.,Jiang, Chenglin.,Liu, Jianguo.,Qin, Ye.,Zhang, Zhongyu.,...&Yan, Chuanwei.(2020).Prediction of viscosity for high-concentrated ternary solution (CH3SO3H + VOSO4 + H2O) in vanadium flow battery.JOURNAL OF MOLECULAR LIQUIDS,297. |
| MLA | Li, Xiangrong,et al."Prediction of viscosity for high-concentrated ternary solution (CH3SO3H + VOSO4 + H2O) in vanadium flow battery".JOURNAL OF MOLECULAR LIQUIDS 297(2020). |
入库方式： OAI收割
来源：金属研究所
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