SmI_2-promoted imino-Reformatsky reaction for facile synthesis of enantioenriched β-amino acid esters
文献类型：期刊论文
| 作者 | Wang Li; Shen Chun; Xu Minghua
|
| 刊名 | Science China. Chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 54期号:1页码:61 |
| 关键词 | β-amino acid ester samarium diiodide N-tert-butanesulfinyl imine Reformatsky reaction β-lactam 3-aminoindan-1one asymmetric synthesis |
| ISSN号 | 1674-7291 |
| 英文摘要 | A facile and efficient method for the stereoselective synthesis of β-amino acid esters via SmI2-promoted imino-Reformatsky reaction is described. Asymmetric addition of tert-butyl bromoacetate to N-tert-butanesulfinyl aldimines afforded β-amino acid esters in moderate to high yields with excellent diastereoselectivities. The synthetic utilities of the tert-butyl β-amino acid esters were expanded by the preparation of β-lactams and 3-aminoindan-1-ones derivatives |
| 语种 | 英语 |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/293172]  |
| 专题 | 中国科学院上海药物研究所 |
| 作者单位 | 中国科学院上海药物研究所 |
| 推荐引用方式 GB/T 7714 | Wang Li,Shen Chun,Xu Minghua. SmI_2-promoted imino-Reformatsky reaction for facile synthesis of enantioenriched β-amino acid esters[J]. Science China. Chemistry,2011,54(1):61. |
| APA | Wang Li,Shen Chun,&Xu Minghua.(2011).SmI_2-promoted imino-Reformatsky reaction for facile synthesis of enantioenriched β-amino acid esters.Science China. Chemistry,54(1),61. |
| MLA | Wang Li,et al."SmI_2-promoted imino-Reformatsky reaction for facile synthesis of enantioenriched β-amino acid esters".Science China. Chemistry 54.1(2011):61. |
入库方式： OAI收割
来源：上海药物研究所
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