Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na-3(MoO4)(IO3) and Na3Cs(MoO2F4)(2)
文献类型：期刊论文
| 作者 | Shi, TT (Shi, Tingting)[ 1,2 ]; Zhang, FF (Zhang, Fangfang)[ 1,2 ]; Li, YH (Li, Yahui)[ 1,2 ]; Gao, L (Gao, Le)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ] ; Pan, S (Pan, Shilie)[ 1,2 ]
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| 刊名 | INORGANIC CHEMISTRY
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| 出版日期 | 2020 |
| 卷号 | 59期号:5页码:3034-3041 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.9b03383 |
| 英文摘要 | The alkali-metal molybdate iodate Na-3(MoO4)(IO3) (I) and mixed-alkali-metal fluoromolybdate Na3Cs(MoO2F4)(2) (II) were obtained via a mild hydrothermal reaction using a "Teflon-pouch" method. I crystallizes in the triclinic space group P (1) over bar, whose structure comprises a 3D backbone made up of isolated [IO3](-) pyramids and [MoO4](2-) tetrahedra connected via 5- and 6-fold coordinated sodium cations. II crystallizes in the monoclinic space group P2(1)/c and comprises isolated [MoO2F4](2-) octahedra with strong out-of-center distortions and the Na+ as well as Cs+ cations acting as interstitial ions. Both compounds have been characterized by infrared (IR) spectra and ultraviolet-visible-near-infrared (UV-vis-NIR) diffuse reflectance spectra. First-principles calculations respectively reveal that they exhibit birefringence values with Delta n = 0.078 and 0.210 at 1064 nm for I and II, and the origin of the birefringence is discussed. |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/7292]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Pan, S (Pan, Shilie)[ 1,2 ] |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, TT ,Zhang, FF ,Li, YH ,et al. Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na-3(MoO4)(IO3) and Na3Cs(MoO2F4)(2)[J]. INORGANIC CHEMISTRY,2020,59(5):3034-3041. |
| APA | Shi, TT ,Zhang, FF ,Li, YH ,Gao, L ,Yang, ZH ,&Pan, S .(2020).Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na-3(MoO4)(IO3) and Na3Cs(MoO2F4)(2).INORGANIC CHEMISTRY,59(5),3034-3041. |
| MLA | Shi, TT ,et al."Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na-3(MoO4)(IO3) and Na3Cs(MoO2F4)(2)".INORGANIC CHEMISTRY 59.5(2020):3034-3041. |
入库方式： OAI收割
来源：新疆理化技术研究所
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