Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation
文献类型：期刊论文
| 作者 | Chen, Qiang5,6; Li, Tianhao5; Zhou, Yiming5; Bi, Yunfei4; Guo, Shuai3; Liu, Xuan5; Kang, Haozhe5; Wang, Mengyue5; Liu, Lei3; Xing, Enhui4 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2020-07-01 |
| 卷号 | 59期号:26页码:12004-12012 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.0c01320 |
| 英文摘要 | Pt nanoparticles encapsulated into zeolite Y (denoted as Pt@Y) exhibited approaching 100% catalytic selectivity to 2,5-bis-(hydroxymethyl)-furan (BHMF) at full conversion of 5-hydroxymethylfurfural (HMF) in the presence of H-2, coupled with good reusability. Zeolite Y constrained HMF to be adsorbed on encapsulated Pt nanoparticle surface via either the end of aldehyde groups or hydroxyl groups in thermodynamically unfavorable end-on mode to enlarge the gap in the activation energies between hydrogenation of aldehyde groups and hydrodehydroxylation of hydroxyl groups to favor selectivity enhancement via avoidance of further hydrodehydroxylation at moderate conditions, which provide a general method to avoid thermodynamics-regulated flat-lying conformation for simultaneous activation on the furan ring, aldehyde, and hydroxyl groups. |
| WOS关键词 | TOTAL-ENERGY CALCULATIONS ; METAL-CLUSTERS ; CO OXIDATION ; NANOPARTICLES ; EFFICIENT ; SIZE ; NANOCRYSTALS ; DISPERSION ; CATALYSTS ; ATOMS |
| 资助项目 | National Natural Science Foundation of China[21706204] ; National Natural Science Foundation of China[51972264] ; China Petroleum AMP; Chemical Corporation[119004-2] ; CAS Pioneer Hundred Talents Program |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000547326800010 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; China Petroleum AMP; Chemical Corporation ; CAS Pioneer Hundred Talents Program |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/41280]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Lei; Xing, Enhui; Yang, Dongyuan |
| 作者单位 | 1.Dalian Inst Chem Phys, Xian Clean Energy Chem Res Inst, Xian 710065, Shaanxi, Peoples R China 2.Shaanxi Yanchang Petr Grp Corp Ltd, Xian 710065, Shaanxi, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 4.Sinopec, Res Inst Petr Proc, Beijing 100083, Peoples R China 5.Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Shaanxi, Peoples R China 6.Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuh Ai 519082, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Qiang,Li, Tianhao,Zhou, Yiming,et al. Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(26):12004-12012. |
| APA | Chen, Qiang.,Li, Tianhao.,Zhou, Yiming.,Bi, Yunfei.,Guo, Shuai.,...&Yang, Dongyuan.(2020).Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(26),12004-12012. |
| MLA | Chen, Qiang,et al."Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.26(2020):12004-12012. |
入库方式： OAI收割
来源：过程工程研究所
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