Catalytic synthesis of methacroleinviathe condensation of formaldehyde and propionaldehyde withl-proline
文献类型：期刊论文
| 作者 | Yu, Jiayuan2,3; Jensen, Anker Degn1; Wang, Lei3; Li, Chunshan3; Zhang, Suojiang3 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2020-07-07 |
| 卷号 | 22期号:13页码:4222-4230 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/d0gc00726a |
| 英文摘要 | Methacrolein (MAL) is an important chemical for the manufacture of methyl methacrylate and a key monomer in many polymerization reactions. In this study,l-proline was investigated as the catalyst for the aldol condensation of formaldehyde and propionaldehyde to produce MAL. The catalytic activity of the reaction system was closely related to the competition between the main reaction synthesizing MAL and the side reaction producing 2-methyl-2-pentenal, which could be modified by adjusting the operating parameters. The influences of several operating conditions, including temperature, reaction time and water content, on the catalytic performance of the system were systematically studiedviaa series of single-factor experiments, and the optimized reaction conditions were obtained. The mechanistic investigationviaESI-MS indicated that the reaction pathway followed the Mannich route. Experimental and theoretical kinetic analyses of thel-proline-catalyzed aldol condensation reaction were performed, and the reaction orders of the reactants were obtained by regression. The results showed thatl-proline was an efficient catalyst for the production of MALviaaldol condensation under mild conditions. |
| WOS关键词 | CROSS-ALDOL CONDENSATION ; ASYMMETRIC ALDOL ; MANNICH ; ORGANOCATALYSIS ; ALDEHYDES ; WATER |
| 资助项目 | National Natural Science Funds[21878293] ; Science Funds for Creative Research Groups of the National Natural Science Foundation of China[21921005] ; Key Research Program of Frontier Sciences[CAS QYZDB-SSW-SLH022] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000545862800015 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Funds ; Science Funds for Creative Research Groups of the National Natural Science Foundation of China ; Key Research Program of Frontier Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/41341]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Lei; Zhang, Suojiang |
| 作者单位 | 1.Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark 2.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Jiayuan,Jensen, Anker Degn,Wang, Lei,et al. Catalytic synthesis of methacroleinviathe condensation of formaldehyde and propionaldehyde withl-proline[J]. GREEN CHEMISTRY,2020,22(13):4222-4230. |
| APA | Yu, Jiayuan,Jensen, Anker Degn,Wang, Lei,Li, Chunshan,&Zhang, Suojiang.(2020).Catalytic synthesis of methacroleinviathe condensation of formaldehyde and propionaldehyde withl-proline.GREEN CHEMISTRY,22(13),4222-4230. |
| MLA | Yu, Jiayuan,et al."Catalytic synthesis of methacroleinviathe condensation of formaldehyde and propionaldehyde withl-proline".GREEN CHEMISTRY 22.13(2020):4222-4230. |
入库方式： OAI收割
来源：过程工程研究所
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